Generalized linear solvation energy model applied to solute partition coefficients in ionic liquid-supercritical carbon dioxide systems

Journal of Chromatography. a
Josef PlanetaMichal Roth

Abstract

Biphasic solvent systems composed of an ionic liquid (IL) and supercritical carbon dioxide (scCO(2)) have become frequented in synthesis, extractions and electrochemistry. In the design of related applications, information on interphase partitioning of the target organics is essential, and the infinite-dilution partition coefficients of the organic solutes in IL-scCO(2) systems can conveniently be obtained by supercritical fluid chromatography. The data base of experimental partition coefficients obtained previously in this laboratory has been employed to test a generalized predictive model for the solute partition coefficients. The model is an amended version of that described before by Hiraga et al. (J. Supercrit. Fluids, in press). Because of difficulty of the problem to be modeled, the model involves several different concepts - linear solvation energy relationships, density-dependent solvent power of scCO(2), regular solution theory, and the Flory-Huggins theory of athermal solutions. The model shows a moderate success in correlating the infinite-dilution solute partition coefficients (K-factors) in individual IL-scCO(2) systems at varying temperature and pressure. However, larger K-factor data sets involving multiple IL-s...Continue Reading

References

Jun 6, 2003·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Vesna Najdanovic-VisakManuel Nunes da Ponte
Feb 17, 2006·Nature·Martyn J EarleJason A Widegren
Jan 17, 2008·Chemical Society Reviews·Natalia V Plechkova, Kenneth R Seddon
Sep 22, 2009·Journal of Chromatography. a·Colin F Poole, Salwa K Poole

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Citations

Jul 12, 2016·Journal of Separation Science·Amaris C Borges-Muñoz, Luis A Colón

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