Generation and Characterization of the First Persistent Platinum(I)-Centered Radical

Angewandte Chemie
Yosi KratishYitzhak Apeloig

Abstract

The first persistent platinum(I)-centered radical was generated by homolytic cleavage of a Pt-HgSiR3 bond of a mercury-substituted platinum(II) complex. The PtI radical was characterized by EPR spectroscopy, chemical trapping experiments, and density functional theory (DFT) calculations.

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Citations

May 23, 2019·Angewandte Chemie·Dirk Leifert, Armido Studer
May 7, 2020·Chemical Communications : Chem Comm·Pablo RíosSalvador Conejero

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