Giant molecular spoked wheels in giant voids: two-dimensional molecular self-assembly goes big

Chemical Communications : Chem Comm
Kazukuni TaharaSteven De Feyter

Abstract

We present here the formation of giant pores in surface-confined molecular networks of a triangular-shaped dehydrobenzo-[12]annulene derivative: the diameter of the pores reaches over 7 nm and the giant pores are used as templates to accommodate a giant molecular spoked wheel, which allows us to observe rotational and adsorption-desorption dynamics of single guest molecules.

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Citations

Feb 9, 2010·Advances in Colloid and Interface Science·Katsuhiko ArigaJonathan P Hill
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