Gold carbene or carbenoid: is there a difference?

Chemistry : a European Journal
Yahui WangAntonio M Echavarren

Abstract

By reviewing the recent progress on the elucidation of the structure of gold carbenes and the definitions of metal carbenes and carbenoids, we recommend to use the term gold carbene to describe gold carbene-like intermediates, regardless of whether the carbene or carbocation extreme resonance dominates. Gold carbenes, because of the weak metal-to-carbene π-back-donation and their strongly electrophilic reactivity, could be classified into the broader family of Fischer carbenes, although their behavior and properties are very specific.

References

Nov 8, 2001·Journal of the American Chemical Society·J P SnyderH J Kim
Apr 10, 2003·Chemical Reviews·Hélène LebelAndré B Charette
May 13, 2004·Chemical Reviews·José BarluengaMiguel Tomás
Jul 23, 2005·Angewandte Chemie·Manuel R FructosPedro J Pérez
Aug 11, 2005·Journal of the American Chemical Society·David J GorinF Dean Toste
Sep 8, 2005·Angewandte Chemie·Cristina Nieto-OberhuberAntonio M Echavarren
Nov 9, 2006·Journal of the American Chemical Society·David J GorinF Dean Toste
Jan 4, 2007·Chemistry : a European Journal·José Marco-Contelles, Elena Soriano
Mar 21, 2007·Journal of the American Chemical Society·Nathan D Shapiro, F Dean Toste
Mar 23, 2007·Nature·David J Gorin, F Dean Toste
Mar 30, 2007·Chemical Communications : Chem Comm·Catelijne H M AmijsAntonio M Echavarren
Apr 13, 2007·Angewandte Chemie·Alois Fürstner, Paul W Davies
Sep 4, 2007·Organic Letters·Catelijne H M AmijsAntonio M Echavarren
Dec 18, 2007·Angewandte Chemie·Andrea CorreaLuigi Cavallo
Feb 9, 2008·Journal of the American Chemical Society·José BarluengaJosefa Flórez
Mar 4, 2008·Journal of the American Chemical Society·Guotao LiLiming Zhang
May 28, 2008·Angewandte Chemie·Alois Fürstner, Louis Morency
Jun 20, 2008·Journal of the American Chemical Society·Alexey FedorovPeter Chen
Jun 26, 2008·Journal of the American Chemical Society·Nathan D Shapiro, F Dean Toste
Jul 19, 2008·Chemical Reviews·Eloísa Jiménez-Núñez, Antonio M Echavarren
Aug 7, 2008·Angewandte Chemie·A Stephen K Hashmi
Aug 14, 2008·Chemical Reviews·M Mar Díaz-Requejo, Pedro J Pérez
Sep 2, 2008·The Journal of Organic Chemistry·Catelijne H M AmijsAntonio M Echavarren
Apr 24, 2009·Chemistry : a European Journal·Ana Escribano-CuestaAntonio M Echavarren
Aug 1, 2009·Chemical Reviews·Karl Heinz Dötz, Joachim Stendel
Aug 4, 2009·Journal of the American Chemical Society·Nathan D ShapiroF Dean Toste
Oct 23, 2009·Chemical Society Reviews·Alois Fürstner
Feb 18, 2010·Nature Chemistry·Diego BenitezF Dean Toste
Jul 14, 2010·Organic & Biomolecular Chemistry·Maximillian S HadfieldAi-Lan Lee
Jul 31, 2010·Angewandte Chemie·Changkun LiJianbo Wang
Oct 12, 2010·Chemistry, an Asian Journal·Patricia Pérez-GalánAntonio M Echavarren
Sep 1, 2009·Nature Chemistry·Antonio M Echavarren
Apr 27, 2011·Accounts of Chemical Research·Israel FernándezMiguel A Sierra
May 14, 2011·Journal of the American Chemical Society·Weimin HeLiming Zhang
Jun 8, 2011·Beilstein Journal of Organic Chemistry·Lei ZhouJianbo Wang
Jun 8, 2011·Beilstein Journal of Organic Chemistry·Pedro J PérezIván Rivilla
Jun 8, 2011·Angewandte Chemie·Dhananjayan VasuRai-Shung Liu
Jun 24, 2011·Journal of the American Chemical Society·Alexey FedorovPeter Chen
Jul 16, 2011·Angewandte Chemie·Biao LuLiming Zhang
Jul 19, 2011·Journal of the American Chemical Society·César R Solorio-AlvaradoAntonio M Echavarren
Aug 2, 2011·Beilstein Journal of Organic Chemistry·Frédéric MiegeJanine Cossy
Oct 25, 2011·Chemistry : a European Journal·Verónica López-CarrilloAntonio M Echavarren

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Citations

Feb 13, 2016·Accounts of Chemical Research·Shaodong ZhouHelmut Schwarz
Jul 22, 2015·Journal of the American Chemical Society·Chao ShuLong-Wu Ye
Oct 11, 2016·Chemistry : a European Journal·Yangyan LiJunliang Zhang
Feb 24, 2017·Angewandte Chemie·Dilip V PatilSeunghoon Shin
Dec 30, 2015·Chemistry : a European Journal·A Stephen K Hashmi
Dec 10, 2016·Chemistry : a European Journal·Miguel BayaJesús Orduna
Dec 15, 2015·Chemical Society Reviews·Lu Liu, Junliang Zhang
Jul 15, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Keith M AzzopardiLeonardo Belpassi
Nov 21, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Dragoş-Adrian RoşcaManfred Bochmann
Jun 9, 2017·Chemistry : a European Journal·Laura Nunes Dos Santos CompridoA Stephen K Hashmi
Jul 18, 2017·Journal of the American Chemical Society·Hiroki NakayamaTetsuhiro Nemoto
Mar 3, 2018·Angewandte Chemie·Nana Kim, Ross A Widenhoefer
Mar 29, 2018·Organic & Biomolecular Chemistry·Cintia VirumbralesRoberto Sanz
Dec 14, 2017·Angewandte Chemie·Abdallah ZeineddineDidier Bourissou
Feb 22, 2018·Chemistry : a European Journal·Wei Fang, Min Shi
Feb 19, 2016·Chemical Society Reviews·Weiwei Zi, F Dean Toste
May 21, 2016·Natural Product Reports·Christos I StathakisAlexandros L Zografos
May 10, 2016·Chemical Communications : Chem Comm·Yuan-Ming SunMin Shi
Jul 15, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Connor J V Halliday, Jason M Lynam
Jul 2, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·René PretoriusMartin Albrecht
Sep 7, 2017·Organic & Biomolecular Chemistry·Long LiLong-Wu Ye
May 24, 2018·Chemical Communications : Chem Comm·Xin-Qi ZhuLong-Wu Ye
Nov 29, 2017·Organic & Biomolecular Chemistry·Xin LiuLong-Wu Ye
Oct 17, 2017·Chemistry : a European Journal·Robert G CardenRoss A Widenhoefer
Jan 16, 2016·Angewandte Chemie·Maximilian JoostDidier Bourissou
Aug 7, 2017·Angewandte Chemie·Anthony PujolNicolas Mézailles
Jul 1, 2018·Chemistry, an Asian Journal·Yuan-Yuan RenShou-Fei Zhu

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