Gold catalysed synthesis of 3-alkoxyfurans at room temperature

Chemical Communications : Chem Comm
Matthew N PennellTom D Sheppard

Abstract

Synthetically important 3-alkoxyfurans can be prepared efficiently via treatment of acetal-containing propargylic alcohols (obtained from the addition of 3,3-diethoxypropyne to aldehydes) with 2 mol% gold catalyst in an alcohol solvent at room temperature. The resulting furans show useful reactivity in a variety of subsequent transformations.

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Citations

Apr 7, 2015·Chemical Reviews·Ruth Dorel, Antonio M Echavarren
Jul 23, 2015·The Journal of Organic Chemistry·Prabhakararao Tharra, Beeraiah Baire
Oct 11, 2016·Organic & Biomolecular Chemistry·Aurélien BlancPatrick Pale
Aug 28, 2018·European Journal of Organic Chemistry·Samantha M GibsonTom D Sheppard
Oct 3, 2017·The Journal of Organic Chemistry·Bing ZhangZunting Zhang
Jun 23, 2018·Bioconjugate Chemistry·Andre H St AmantJavier Read de Alaniz

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