Heck-like Reactions Involving Heteroatomic Electrophiles

European Journal of Organic Chemistry
Bojan Vulovic, Donald A Watson

Abstract

Since the discovery of the Heck reaction in the early seventies, this reaction has become a powerful tool in synthetic organic chemistry. By employing heteroatomic instead of traditional carbon electrophiles, the Heck reaction shows an intriguing flexibility. These "hetereoatomic-Heck reactions" reinvigorate the area, offering new routes to highly useful synthetic precursors and structural motifs present in biologically active compounds. This microreview focuses on early developments leading to the heteroatomic-Heck reactions (silyl-Heck, boryl-Heck and intramolecular aza-Heck), current state of the emerging area, as well as that of a few related processes.

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Citations

Jul 17, 2019·Angewandte Chemie·Feiyang XuDonald A Watson
May 28, 2021·Organic Letters·Olamide O IdowuDonald A Watson
Feb 19, 2019·Journal of the American Chemical Society·Xiaofeng MaJohn F Bower
Sep 30, 2017·Organic Letters·Sarah B KrauseDonald A Watson
Jun 12, 2019·Chemical Reviews·Katerina M Korch, Donald A Watson
Apr 5, 2018·Organic Letters·Kazuhiro MatsumotoYumiko Nakajima
Aug 31, 2021·Organic Letters·Katerina M Korch, Donald A Watson
Dec 31, 2021·Chemical Reviews·Bogdan MarciniecHieronim Maciejewski

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