Heterobimetallic Pd-K carbene complexes via one-electron reductions of palladium radical carbenes

Chemical Science
Peng CuiVlad M Iluc

Abstract

Heterobimetallic Pd-K carbenes featuring Pd-Ccarbene-K moieties were synthesized via an unprecedented sequential substitution/reduction reaction from a radical precursor, [{PC˙(sp2)P} tBuPdI] ([PC(sp2)P] tBu = bis[2-(di-iso-propylphosphino)-4-tert-butylphenyl]methylene). Polymeric structures were observed in the solid state for the heterobimetallic compounds that can be interrupted in the presence of a donor solvent.

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Citations

Jan 3, 2019·Chemistry : a European Journal·Marc DevillardJarl Ivar van der Vlugt
Mar 21, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Peng CuiVlad M Iluc
Apr 9, 2021·Journal of the American Chemical Society·Melissa R Hoffbauer, Vlad M Iluc
Jun 20, 2021·Angewandte Chemie·Qingyang WangRowan D Young

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Methods Mentioned

BETA
X-ray
NMR
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Software Mentioned

Gaussian

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