Heterobismetal complexes of [26]hexaphyrin(1.1.1.1.1.1)

Inorganic Chemistry
Shigeki Mori, Atsuhiro Osuka

Abstract

Au(III)Cu(III) and Au(III)Rh(I) heterobismetal complexes of meso-aryl-substituted [26]hexaphyrin were rationally prepared from a monometal Au(III) complex. The Au(III)Cu(III) complex is an aromatic molecule with a rectangular shape, while Au(III)Rh(I) complexes are out-of-plane macrocycles, being either aromatic or antiaromatic depending upon the number of conjugated pi electrons. The 26pi Au(III)Rh(I) complex was converted into an aromatic and planar 26pi Au(III)Rh(III) complex via double C-H bond activation upon refluxing in pyridine.

References

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Jun 2, 2005·Journal of the American Chemical Society·Shigeki Mori, Atsuhiro Osuka
Jun 7, 2005·Inorganic Chemistry·Shigeki MoriAtsuhiro Osuka
Nov 24, 2006·Chemistry : a European Journal·Yiho KamimuraAtsuhiro Osuka
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Jan 18, 2008·Journal of the American Chemical Society·Jong Kang ParkDongho Kim

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Citations

Jun 27, 2009·Chemical Communications : Chem Comm·Harapriya RathAtsuhiro Osuka
Aug 19, 2016·Chemical Reviews·Takayuki Tanaka, Atsuhiro Osuka
Sep 23, 2016·Chemical Reviews·Timothy D Lash
Mar 6, 2018·Angewandte Chemie·Biju BasumataryJeyaraman Sankar
Mar 18, 2015·Chemistry, an Asian Journal·Miłosz Pawlicki, Lechosław Latos-Grażyński
Feb 1, 2014·Chemistry, an Asian Journal·Timothy D Lash
Mar 26, 2014·Chemistry : a European Journal·Ji-Young ShinAtsuhiro Osuka
May 21, 2014·Chemistry : a European Journal·Shin-ichiro IshidaAtsuhiro Osuka
Feb 2, 2010·Chemistry : a European Journal·Jacek Wojaczyński, Lechosław Latos-Grazyński
Oct 16, 2015·Chemistry : a European Journal·Mercedes AlonsoFrank De Proft
Apr 26, 2013·Chemistry, an Asian Journal·Koji NaodaAtsuhiro Osuka
May 12, 2010·Angewandte Chemie·Geneva R Peterson, Nick Bampos
Apr 30, 2013·Chemistry : a European Journal·Tomoki Yoneda, Atsuhiro Osuka
Apr 15, 2011·Angewandte Chemie·Shohei Saito, Atsuhiro Osuka
Apr 12, 2013·Chemistry : a European Journal·Lina K BluschFranc Meyer
Oct 16, 2014·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Atsuhiro Osuka
Mar 23, 2012·Organic & Biomolecular Chemistry·Janusz SkoniecznyLudmiła Szterenberg
Feb 23, 2017·Chemical Reviews·Bartosz SzyszkoLechosław Latos-Grażyński

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