Heterogeneity within a Mesoporous Metal-Organic Framework with Three Distinct Metal-Containing Building Units

Journal of the American Chemical Society
Binbin TuQiaowei Li

Abstract

Materials built from multiple constituents have revealed emerging properties that are beyond linear integration of those from single components. We report a mesoporous metal-organic framework made from three geometrically distinct metal-containing secondary building units (SBUs) as a result of topological induction. The combinations of the Cu-based triangular, Zn-based octahedral, and Zn-based square pyramidal SBUs have created four types of cages in the network, despite that only one organic linker pyrazolecarboxylate was used. The longest distance for molecules maneuvering inside the largest cage is 5.2 nm. Furthermore, the complex and diversified pore environments allow the installation of various new functionalities in the framework as well as the expedited Ag nanoparticle formation in the pores. As presented in the molecule movement diagram, the crystal has provided specific arrangements of cages and apertures with distinct chemical features for guests transporting between the pores.

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Citations

May 7, 2016·Journal of the American Chemical Society·Shuai YuanHong-Cai Zhou
Jun 28, 2016·Journal of the American Chemical Society·Shuai YuanHong-Cai Zhou
Sep 15, 2016·Chemical Reviews·Alexander SchoedelOmar M Yaghi
Feb 15, 2017·Journal of the American Chemical Society·Yong-Sheng WeiThomas C W Mak
Nov 3, 2017·Chemical Communications : Chem Comm·Zijian LiYong Cui
Aug 19, 2017·Faraday Discussions·Bunyarat RungtaweevoranitOmar M Yaghi
Feb 13, 2018·Advanced Materials·Shuai YuanHong-Cai Zhou
Feb 25, 2018·Nature Communications·Shuai YuanHong-Cai Zhou
Apr 13, 2019·Angewandte Chemie·Mohammad Yaser MasoomiHermenegildo Garcia
May 23, 2020·Chemistry : a European Journal·Matthew Brian FreemanChristopher Bejger
Feb 6, 2020·Topics in Current Chemistry·Alexander Schoedel, Sahar Rajeh
Mar 31, 2021·Angewandte Chemie·Ralph FreundChristian S Diercks
Jan 16, 2019·Journal of the American Chemical Society·Tian-You ZhouShane G Telfer
Aug 5, 2017·Journal of the American Chemical Society·Hasmukh A PatelJ Fraser Stoddart
Sep 6, 2017·Journal of the American Chemical Society·Cong-Cong LiangYue-Biao Zhang
Dec 10, 2016·Journal of the American Chemical Society·Omar M Yaghi
May 4, 2018·Journal of the American Chemical Society·Patrick F MuldoonNathaniel L Rosi
Nov 20, 2018·Journal of the American Chemical Society·Qi LiuHexiang Deng
Oct 20, 2021·Journal of the American Chemical Society·Zhiyong LuJoseph T Hupp

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