Heteronuclear 3 d/Dy(III) coordination clusters as catalysts in a domino reaction

Chemistry : a European Journal
Kieran GriffithsGeorge E Kostakis

Abstract

Three isoskeletal tetranuclear coordination clusters with general formula [M(II) 2 Dy(III) 2 L4 (EtOH)6 ](ClO4 )2 ⋅2 EtOH, (M=Co, 1; M=Ni, 2) and [Ni(II) 2 Dy(III) 2 L4 Cl2 (CH3 CN)2 ]⋅2 CH3 CN (3), have been synthesized and characterized. These air-stable compounds, and in particular 3, display efficient homogeneous catalytic behavior in the room-temperature synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere.

References

Feb 26, 2008·Angewandte Chemie·Xiang-Jian KongLan-Sun Zheng
Oct 6, 2010·Inorganic Chemistry·Constantina PapatriantafyllopoulouGeorge Christou
Oct 26, 2011·Inorganic Chemistry·Kartik Chandra MondalAnnie K Powell
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Citations

Aug 19, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Marius Andruh
Jun 20, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Benjamin BerkoffGeorge E Kostakis
Mar 6, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Stavroula I SampaniGeorge E Kostakis
Apr 6, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Susanta HazraSasankasekhar Mohanta
Jun 2, 2016·Chemical Communications : Chem Comm·Kieran GriffithsGeorge E Kostakis
Jun 1, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Panagiota S PerlepeTheocharis C Stamatatos
Dec 17, 2015·Chemical Communications : Chem Comm·Dimitris I AlexandropoulosTheocharis C Stamatatos
May 18, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Ruilian ZhangWeisheng Liu
Feb 3, 2018·Chemistry : a European Journal·Rafael F A GomesCarlos A M Afonso
Jul 28, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Kieran Griffiths, George E Kostakis
Nov 30, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Prashant KumarGeorge E Kostakis
Nov 16, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Marek MachataZdeněk Trávníček
Jan 25, 2018·Organic & Biomolecular Chemistry·Charlie VerrierFlorence Popowycz
Feb 6, 2018·The Journal of Organic Chemistry·Rafael F A GomesCarlos A M Afonso
Jun 12, 2021·ChemMedChem·Rafael F A GomesCarlos A M Afonso

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