Hg(II)...Pd(II) metallophilic interactions

Journal of the American Chemical Society
Mieock KimFrançois P Gabbaï

Abstract

Reaction of bis(pentafluorophenyl)mercury (1) with the Pd(II) complexes [Pd(salophen)] (I, salophen = N,N'-disalicylidene-o-phenylenediaminate) and [Pd(N--C)(OAc)]2 (II, N--C = (2-(2-pyridyl)phenyl-C,N)) leads to the formation of the supramolecular complexes [1-(I)2] and [1-(II)2] in which the mercury synthon is sandwiched by two molecules of the palladium complex. These complexes, whose formation can be observed in solution by UV-vis spectroscopy, have been fully characterized. The short Hg-Pd distances of 3.2841(2) A in [1-(I)2] and 3.1065(8) A in [1-(II)2] indicate the presence of a Hg-Pd metallophilic interaction which, at least for [1-(II)2], is complemented by a Pd(II)-->Hg(II) donor-or component.

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Citations

May 13, 2011·Journal of the American Chemical Society·Daniel SerraPeter Chen
Jan 26, 2013·Journal of the American Chemical Society·María José MayoralGustavo Fernández
Apr 1, 2009·Journal of the American Chemical Society·Marc-Etienne Moret, Peter Chen
Dec 22, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Allan J Canty
Apr 7, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Linda H Doerrer
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Feb 13, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Mitsukimi TsunodaFrançois P Gabbaï
Apr 11, 2018·Angewandte Chemie·Alain C Tagne KuateFrieder Jäkle
Jun 2, 2018·Chemical Communications : Chem Comm·Jorge Echeverría
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