High-Nuclearity Heterometallic tert-Butylethynide Clusters Assembled with tert-Butylphosphonate

Chemistry : a European Journal
Guang-Xiong DuanThomas C W Mak

Abstract

tert-Butylphosphonic acid and lanthanide precursors were employed to construct two high-nuclearity hybrid silver(I)-ytterbium(III) phosphonate clusters: compound 1 consists of a Ag16 ethynide cluster fused with a trinuclear hydroxoytterbium phosphonate cluster, whereas compound 2 is composed of two Ag16 ethynide clusters bridged by a hexanuclear oxo/hydroxoytterbium phosphonate cluster. Using transition-metal-substituted lacunary polyoxotungstates in place of the lanthanide reactant, new phosphonate-functionalized silver(I)-copper(II) ethynide clusters [Ag34 Cu6 (3) and Ag37 Cu6 (4)] and silver(I) ethynide clusters [Ag51 (5) and Ag72 (6)] were obtained. The structures of complexes 3-6 feature core-shell arrangements, in which silver(I)-copper(II) or silver(I) ethynide cluster shells stabilized by peripheral phosphonate ligands enclose different kinds of tungstate core templates.

References

Oct 10, 2001·Angewandte Chemie·Daniela RaisDavid J. Williams
Nov 11, 2008·Chemical Communications : Chem Comm·Shu-Dan Bian, Quan-Ming Wang
Dec 2, 2009·Journal of the American Chemical Society·Guang-Gang GaoThomas C W Mak
Jun 10, 2010·Angewandte Chemie·Franziska Gruber, Martin Jansen
Jul 30, 2010·Angewandte Chemie·Jian-Qiang WangThomas F Fässler
Feb 26, 2011·Journal of the American Chemical Society·Yun-Peng Xie, Thomas C W Mak
Mar 29, 2011·Angewandte Chemie·Yan-Zhen ZhengRichard E P Winpenny
Dec 15, 2011·Chemical Communications : Chem Comm·Yun-Peng Xie, Thomas C W Mak
Dec 17, 2011·Journal of the American Chemical Society·Yan-Zhen ZhengRichard E P Winpenny
Jul 26, 2012·Chemistry : a European Journal·Ying Xiao, Quan-Ming Wang
Aug 25, 2012·Chemical Society Reviews·Olaf FuhrDieter Fenske
Mar 29, 2013·Chemical Communications : Chem Comm·Yu-Yang LiJing-Lin Zuo
Dec 4, 2013·Chemical Society Reviews·Yan-Zhen ZhengRichard E P Winpenny
Jul 11, 2014·Coordination Chemistry Reviews·Joseph W Sharples, David Collison
Aug 16, 2014·Chemistry : a European Journal·Bo LiThomas C W Mak
Jan 15, 2015·Inorganic Chemistry·Mariko KurasawaTomoji Ozeki
Jan 23, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Chao-Yu SongGuang-Gang Gao
Jan 30, 2015·Angewandte Chemie·Rajendra S DhayalC W Liu
Apr 9, 2015·Chemistry, an Asian Journal·Xiao-Yu LiLan-Sun Zheng
May 20, 2015·Accounts of Chemical Research·Quan-Ming WangKuan-Guan Liu
Jun 30, 2015·Chemical Reviews·Joydeb Goura, Vadapalli Chandrasekhar
Oct 16, 2015·Angewandte Chemie·Eric J L McInnesRichard E P Winpenny
Nov 19, 2015·Angewandte Chemie·Yun-Peng XieThomas C W Mak
Sep 20, 2017·Journal of the American Chemical Society·Ling-Yu GuoLan-Sun Zheng
Nov 1, 2017·Proceedings of the National Academy of Sciences of the United States of America·Zhi WangLan-Sun Zheng
Dec 6, 2017·Chemistry : a European Journal·Zhi WangLan-Sun Zheng

❮ Previous
Next ❯

Citations

Aug 29, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Jun-Ling JinXing Lu
Aug 28, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Yang-Lin ShenXing Lu
Dec 12, 2018·Inorganic Chemistry·Jun-Ling JinXing Lu
Oct 8, 2021·Chemical Communications : Chem Comm·Sukhen BalaRaju Mondal
Oct 28, 2021·Chemical Reviews·Alexander V VirovetsManfred Scheer

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.