High-nuclearity silver ethynide clusters containing polynucleating oxygen donor ligands

Dalton Transactions : an International Journal of Inorganic Chemistry
Jun-Ling JinXing Lu

Abstract

Polynucleating oxygen donor ligands as precursors have been employed to construct three high-nuclearity heterometallic ethynide clusters. Compound 2 consists of a Cl@Ag12 ethynide cluster capped by two trinuclear organooxotin phosphonate clusters [(nBuSn)3(μ3-O)(tBuPO3)3(OMe)(OH)2]2-. Compound 3 consists of a Ag8 ethynide cluster fused with a nonanuclear oxo-bismuth phosphonate cluster [Bi9O6(tBuPO3)9(tBuPO3H)]4-, while compound 4 is composed of two Cl@Ag15 ethynide clusters bridged by a hexanuclear oxo/hydroxo-bismuth phosphonate cluster [Bi6O4(OH)4(tBuPO3)6(hfac)2(CF3COO)2]10-.

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Citations

Aug 28, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Yang-Lin ShenXing Lu
Apr 20, 2021·Inorganic Chemistry·Yang-Lin ShenXing Lu
Oct 28, 2021·Chemical Reviews·Alexander V VirovetsManfred Scheer

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