High-Oxidation-State 3d Metal (Ti-Cu) Complexes with N-Heterocyclic Carbene Ligation

Chemical Reviews
Jun ChengLiang Deng

Abstract

High-oxidation-state 3d metal species have found a wide range of applications in modern synthetic chemistry and materials science. They are also implicated as key reactive species in biological reactions. These applications have thus prompted explorations of their formation, structure, and properties. While the traditional wisdom regarding these species was gained mainly from complexes supported by nitrogen- and oxygen-donor ligands, recent studies with N-heterocyclic carbenes (NHCs), which are widely used for the preparation of low-oxidation-state transition metal complexes in organometallic chemistry, have led to the preparation of a large variety of isolable high-oxidation-state 3d metal complexes with NHC ligation. Since the first report in this area in the 1990s, isolable complexes of this type have been reported for titanium(IV), vanadium(IV,V), chromium(IV,V), manganese(IV,V), iron(III,IV,V), cobalt(III,IV,V), nickel(IV), and copper(II). With the aim of providing an overview of this intriguing field, this Review summarizes our current understanding of the synthetic methods, structure and spectroscopic features, reactivity, and catalytic applications of high-oxidation-state 3d metal NHC complexes of titanium to copper. In...Continue Reading

References

Apr 11, 2000·Accounts of Chemical Research·D SchröderH Schwarz
Oct 30, 2001·Journal of Biological Inorganic Chemistry : JBIC : a Publication of the Society of Biological Inorganic Chemistry·Z Gross
Nov 17, 2001·Chemical Reviews·M A Peña, J L Fierro
Dec 26, 2001·Chemical Reviews·Didier BourissouGuy Bertrand
Sep 19, 2002·Journal of the American Chemical Society·David M JenkinsJonas C Peters
Nov 21, 2002·Journal of the American Chemical Society·Kun QinKlaus H Theopold
Jan 30, 2003·Journal of the American Chemical Society·Colin D AbernethyMichelle K Taylor
Apr 10, 2003·Journal of the American Chemical Society·Sunita ThyagarajanKlaus H Theopold
Sep 4, 2003·Journal of the American Chemical Society·Theodore A Betley, Jonas C Peters
Sep 19, 2003·Chemical Communications : Chem Comm·Hidenori AiharaHiroyuki Kawaguchi
Oct 2, 2003·Journal of the American Chemical Society·Xile HuKarsten Meyer
Feb 12, 2004·Chemical Reviews·Anna L Gavrilova, Brice Bosnich
Apr 15, 2004·Journal of the American Chemical Society·Xuliang DaiTimothy H Warren
May 20, 2004·Journal of the American Chemical Society·Theodore A Betley, Jonas C Peters
Sep 9, 2004·Chemical Reviews·Bernard MeunierSason Shaik
Oct 14, 2004·Journal of the American Chemical Society·Xile HuKarsten Meyer
Dec 17, 2004·Journal of the American Chemical Society·Xile Hu, Karsten Meyer
Feb 5, 2005·Angewandte Chemie·Daniel T ShayKlaus H Theopold
Jun 2, 2005·Journal of the American Chemical Society·Devesh KumarSason Shaik
Jul 26, 2005·Chemical Communications : Chem Comm·Claude Y LegaultAndré B Charette
Aug 11, 2005·Journal of the American Chemical Society·Elzbieta KogutTimothy H Warren
Jan 27, 2006·Dalton Transactions : an International Journal of Inorganic Chemistry·David PughAndreas A Danopoulos
Mar 3, 2006·Current Opinion in Chemical Biology·John W Peters, Robert K Szilagyi
Mar 4, 2006·Chemical Communications : Chem Comm·Dipti PatelPolly L Arnold
Apr 13, 2006·Journal of the American Chemical Society·Christine M ThomasJonas C Peters
Apr 20, 2006·Journal of the American Chemical Society·Suzanne C BartPaul J Chirik
Jun 3, 2006·Science·John F BerryKarl Wieghardt

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Citations

Feb 6, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Toshiki NishiuraShiro Hikichi
Jan 4, 2019·Chemistry : a European Journal·Claudia SchremmerFranc Meyer
Mar 26, 2019·Chemistry : a European Journal·Jean-Charles BruyereSamuel Dagorne
Sep 3, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Marc BaltrunStephan Hohloch
Sep 19, 2019·Angewandte Chemie·Hao-Ching ChangShengfa Ye
Oct 2, 2020·Chemical Communications : Chem Comm·Kaijie WeiWei Yu
Aug 23, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Chandrakanta DashH V Rasika Dias
Nov 25, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Ryosuke HaraguchiShin-Ichi Fukuzawa
Apr 10, 2020·Inorganic Chemistry·Lisa GravoglKarsten Meyer
Feb 26, 2019·Chemical Reviews·Derek J Durand, Natalie Fey
Nov 20, 2020·Inorganic Chemistry·Yafei GaoJeremy M Smith
Apr 7, 2020·Journal of the American Chemical Society·Liam S SharninghausenMelanie S Sanford
Aug 28, 2021·Chemical Science·Qun ZhaoMichal Szostak

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