High Volumetric Hydrogen Adsorption in a Porous Anthracene-Decorated Metal-Organic Framework

Inorganic Chemistry
Yong YanMartin Schröder

Abstract

We report an unprecedented ligand-based binding domain for D2 within a porous metal-organic framework (MOF) material as confirmed by neutron powder diffraction studies of D2-loaded MFM-132a. A tight pocket of 6 Å diameter is formed by the close packing of three anthracene panels, and it is here rather than the open metal sites where D2 binds preferentially. As a result, MFM-132a shows exceptional volumetric hydrogen adsorption (52 g L-1 at 60 bar and 77 K) and the highest density of adsorbed H2 within its pores among all the porous materials reported to date under the same conditions. This work points to a new direction for H2 storage in porous materials using polyaromatic ligand-based sites.

References

Nov 20, 2001·Nature·L Schlapbach, A Züttel
May 6, 2004·Journal of the American Chemical Society·Jesse L C RowsellOmar M Yaghi
Mar 23, 2006·Journal of the American Chemical Society·Daofeng SunHong-Cai Zhou
Dec 7, 2006·Journal of the American Chemical Society·Vanessa K PetersonCameron J Kepert
Dec 21, 2006·Journal of the American Chemical Society·Mircea DincăJeffrey R Long
Oct 31, 2007·Journal of the American Chemical Society·Steven S KayeJeffrey R Long
May 16, 2008·Chemical Communications : Chem Comm·Annemieke W C van den Berg, Carlos Otero Areán
Aug 9, 2008·Angewandte Chemie·Mircea Dincă, Jeffrey R Long
Feb 20, 2009·Chemical Communications : Chem Comm·Yong YanMartin Schröder
Mar 25, 2009·Chemistry : a European Journal·Sihai YangMartin Schröder
Apr 11, 2009·Small·Jonathan GermainFrantisek Svec
Apr 23, 2009·Chemical Society Reviews·Leslie J MurrayJeffrey R Long
Jul 15, 2009·Angewandte Chemie·Ulrich EberleFerdi Schüth
Mar 5, 2010·Journal of the American Chemical Society·Yong YanMartin Schröder
Jul 3, 2010·Science·Hiroyasu FurukawaOmar M Yaghi
Dec 23, 2010·Journal of the American Chemical Society·Baishu ZhengMichael J Zaworotko
Jun 29, 2011·Journal of the American Chemical Society·Norifumi KishiMichito Yoshizawa
Sep 8, 2011·Chemistry : a European Journal·Yong YanMartin Schröder
Dec 24, 2011·Chemical Reviews·Myunghyun Paik SuhDae-Woon Lim
Oct 31, 2013·Accounts of Chemical Research·Yong YanMartin Schröder
Oct 31, 2013·Chemical Society Reviews·Michito Yoshizawa, Jeremy K Klosterman
Aug 4, 2016·Journal of the American Chemical Society·Dana J LevineJeffrey R Long
Aug 5, 2017·Journal of the American Chemical Society·Yong YanMartin Schröder

❮ Previous
Next ❯

Citations

Mar 1, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Josep M Oliva-EnrichJosé Elguero

❮ Previous
Next ❯

Methods Mentioned

BETA
difference neutron scattering

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.