Highly active, chemo- and regioselective Yb(II) and Sm(II) catalysts for the hydrophosphination of styrene with phenylphosphine

Chemistry : a European Journal
Ivan V BasalovAlexander A Trifonov

Abstract

Stable heteroleptic amido Yb(II) and Sm(II) complexes bearing aminoether-phenolate ligands and devoid of coordinated solvent have been structurally characterized. They afford highly active, chemoselective and, in the case of monoadditions, 100 % anti-Markovnikov regiospecific catalysts (down to 0.04 mol % loading) for the hydrophosphination of styrene with PhPH2 under mild conditions.

References

Jun 13, 2002·Chemical Reviews·Gary A Molander, Jan Antoinette C Romero
Oct 8, 2004·Journal of the American Chemical Society·Amber M Kawaoka, Tobin J Marks
Apr 28, 2005·Journal of the American Chemical Society·Amber M Kawaoka, Tobin J Marks
Jul 17, 2008·Angewandte Chemie·Sjoerd Harder
Aug 30, 2008·Chemical Reviews·Thomas E MüllerMizuki Tada
May 22, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Charles J Weiss, Tobin J Marks
Jun 18, 2014·Journal of the American Chemical Society·Michael B GhebreabRory Waterman

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Citations

Nov 29, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·A A TrifonovA A Kissel
Jan 15, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·John P W StelmachRory Waterman
Nov 19, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Julian Rodger Frederic Pritzwald-StegmannEvamarie Hey-Hawkins
Nov 5, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Christine A BangeRory Waterman
Jun 8, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Natalia V ForosenkoAlexander A Trifonov
Jun 23, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Yu ZhangYingming Yao
Oct 20, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Leah GajeckiAllen G Oliver
Jun 30, 2016·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Yann Sarazin, Jean-François Carpentier
Jul 14, 2016·Chemistry : a European Journal·Christine A Bange, Rory Waterman
Nov 20, 2016·Chemistry : a European Journal·Alexander N SelikhovAlexander A Trifonov
Oct 29, 2020·Chemical Communications : Chem Comm·Steven G Dannenberg, Rory Waterman
Jul 8, 2021·Organic & Biomolecular Chemistry·Indrani Banerjee, Tarun K Panda
Dec 21, 2018·Journal of the American Chemical Society·Xiaojuan LiuYaofeng Chen

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