Highly concentrated "solutions" of metal cations in ionic liquids: current status and future challenges

Physical Chemistry Chemical Physics : PCCP
Cinzia Chiappe, Marco Malvaldi

Abstract

In this article we summarize a series of conditions that allow highly concentrated "solutions" of metal cations in ionic liquids to be obtained, evidencing structural features and some of the most important physico-chemical properties of these systems. We try to emphasize aspects and problems that are not conventionally discussed in detail in the literature. In particular, we provide a full length discussion on the topics of: (i) solvation of metal salts in ionic liquids, (ii) anion coordinating ability and homologous and heterogeneous complexes. A brief outlook into future perspectives of metal containing ILs is also provided.

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Citations

Jan 5, 2012·Chemical Communications : Chem Comm·Pengfei ZhangHaoran Li
Oct 8, 2013·Physical Chemistry Chemical Physics : PCCP·Stijn SchaltinJan Fransaer
Aug 19, 2015·Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy·Ian Harvey ArellanoPhillip Pendleton
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Aug 26, 2020·Chemistry : a European Journal·Christian BalischewskiAlexandra Kelling
Jun 2, 2015·Chemical Reviews·Robert HayesRob Atkin

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