Highly efficient regioselective hydrosilylation of allenes using a [(3IP)Pd(allyl)]OTf catalyst; first example of allene hydrosilylation with phenyl- and diphenylsilane

Chemical Communications : Chem Comm
Hosein Tafazolian, Joseph A R Schmidt

Abstract

A [(3IP)Pd(allyl)]OTf complex was shown to function efficiently and regioselectively in allene hydrosilylation with phenyl- and diphenylsilane. The catalyst also proved to be highly active for allene hydrosilylation employing a wide range of silanes, each of which produced a single regioisomer.

References

Jan 31, 2009·Chemistry : a European Journal·Andrew R Shaffer, Joseph A R Schmidt
Dec 3, 2009·Organic Letters·Ralph MoserBruce H Lipshutz
Sep 3, 2010·Journal of the American Chemical Society·Jessica Y WuTobias Ritter
Oct 2, 2013·Journal of the American Chemical Society·Zachary D MillerJohn Montgomery
Mar 22, 2014·Journal of the American Chemical Society·Sarah E ParkerTobias Ritter
Nov 18, 2014·Journal of the American Chemical Society·M Taylor HaynesJohn Montgomery

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Citations

Sep 4, 2015·Organic Letters·Marios Kidonakis, Manolis Stratakis
Jun 17, 2015·Angewandte Chemie·Zachary D MillerJohn Montgomery
Apr 11, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Hosein TafazolianJoseph A R Schmidt
May 21, 2019·Chemistry : a European Journal·Marios KidonakisManolis Stratakis

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