Highly photoconducting π-stacked polymer accommodated in coordination nanochannels

Journal of the American Chemical Society
Takashi UemuraSusumu Kitagawa

Abstract

We report on the formation of single poly(N-vinylcarbazole) (PVCz) chains in one-dimensional channels of [La(1,3,5-benzenetrisbenzoate)](n), where the side carbazolyl groups of the confined PVCz are effectively π-stacked. This ideal conformation of PVCz chains in the coordination nanochannels contributed to a drastic increase in hole mobility, which was 5 orders of magnitude higher than that in the bulk state. It is also noteworthy that PVCz isolated from the nanchannels still had a high hole mobility.

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Citations

Jul 13, 2016·The Journal of Physical Chemistry Letters·Barun DharaNirmalya Ballav
Aug 4, 2016·Journal of the American Chemical Society·Benjamin Le OuayTakashi Uemura
Apr 4, 2017·Chemical Society Reviews·Takashi KitaoTakashi Uemura
Apr 7, 2016·Chemical Society Reviews·Cho Rong KimSusumu Kitagawa
Nov 20, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Kolleboyina JayaramuluTapas Kumar Maji
Nov 4, 2017·Chemical Communications : Chem Comm·Guangfeng LiuQichun Zhang
Jun 15, 2017·Chemical Communications : Chem Comm·Yuichiro KobayashiTakashi Uemura
Jan 21, 2014·Chemistry : a European Journal·Takashi Uemura
Nov 15, 2014·Angewandte Chemie·Wei-Wei XiongQichun Zhang
Sep 28, 2018·Chemical Communications : Chem Comm·Shuto MochizukiTakashi Uemura
Apr 5, 2019·Chemistry : a European Journal·Teppei YamadaNobuo Kimizuka
May 16, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Pablo Salcedo-AbrairaPatricia Horcajada
May 13, 2017·Materials Horizons·Tiesheng WangStoyan K Smoukov
Jun 9, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Yannan Lu, David James Young
Apr 12, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiu-Li WangGuo-Cheng Liu
Aug 31, 2020·Environmental Science and Pollution Research International·Onome EjeromedogheneMichael O Daramola
Dec 20, 2018·Chemical Communications : Chem Comm·Tomoya IizukaTakashi Uemura
Jan 14, 2021·Chemistry : a European Journal·Wenjuan XuHongwei Hou
May 29, 2015·Journal of the American Chemical Society·Shuangbing HanBartosz A Grzybowski
May 11, 2017·The Journal of Physical Chemistry. B·Paul D Greenstein, Leah B Casabianca
May 8, 2014·Journal of the American Chemical Society·Liang GaoZhe-Ning Chen
Jan 3, 2020·Chemical Reviews·Mark KalajSeth M Cohen

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