Hole-hole Tamm-Dancoff-approximated density functional theory: A highly efficient electronic structure method incorporating dynamic and static correlation

The Journal of Chemical Physics
Christoph BannwarthTodd J Martínez

Abstract

The study of photochemical reaction dynamics requires accurate as well as computationally efficient electronic structure methods for the ground and excited states. While time-dependent density functional theory (TDDFT) is not able to capture static correlation, complete active space self-consistent field methods neglect much of the dynamic correlation. Hence, inexpensive methods that encompass both static and dynamic electron correlation effects are of high interest. Here, we revisit hole-hole Tamm-Dancoff approximated (hh-TDA) density functional theory for this purpose. The hh-TDA method is the hole-hole counterpart to the more established particle-particle TDA (pp-TDA) method, both of which are derived from the particle-particle random phase approximation (pp-RPA). In hh-TDA, the N-electron electronic states are obtained through double annihilations starting from a doubly anionic (N+2 electron) reference state. In this way, hh-TDA treats ground and excited states on equal footing, thus allowing for conical intersections to be correctly described. The treatment of dynamic correlation is introduced through the use of commonly employed density functional approximations to the exchange-correlation potential. We show that hh-TDA i...Continue Reading

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Citations

Nov 20, 2020·Chemical Reviews·Julia Westermayr, Philipp Marquetand
Apr 23, 2021·Journal of Chemical Theory and Computation·Ruibin Liang
Oct 16, 2020·The Journal of Physical Chemistry. a·Ryan J DiRisioBenjamin J G Rousseau
Aug 14, 2020·Journal of Chemical Theory and Computation·Jimmy K YuTodd J Martínez
Nov 18, 2021·Physical Chemistry Chemical Physics : PCCP·Ruibin LiangAmirhossein Bakhtiiari

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