Homochiral metal phosphonate nanotubes

Chemical Communications : Chem Comm
Xun-Gao LiuHiroshi Kitagawa

Abstract

A new type of homochiral metal-organic nanotubular structures based on metal phosphonates are reported, namely, (R)- or (S)-[M(pemp)(H2O)2][M = Co(II) (1), Ni(II) (2)] [pemp(2-) = (R)- or (S)-(1-phenylethylamino)methylphosphonate]. In these compounds, the tube-walls are purely inorganic, composed of metal ions and O-P-O bridges. The cavity of the nanotube is hydrophilic with one coordination water pointing towards the center, while the outer periphery of the nanotube is hydrophobic, decorated by the phenylethyl groups of pemp(2-). The thermal stabilities, adsorption and proton conductivity properties are investigated.

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Citations

Sep 10, 2016·Chemistry : a European Journal·Weiting YangZhong-Ming Sun
Oct 14, 2021·Journal of the American Chemical Society·Jia-Ge JiaLi-Min Zheng

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