Homoleptic uranium and lanthanide phosphinodiboranates

Chemical Communications : Chem Comm
Anastasia V BlakeScott R Daly

Abstract

Here we report a new class of homoleptic f-element borohydride complexes called phosphinodiboranates. Treating UI3(1,4-dioxane)1.5, NdI3, or ErI3, with three equiv. of K(H3BPtBu2BH3) in Et2O yielded M2(H3BPtBu2BH3)6, where M = U, Nd, and Er. All three complexes form solid-state dimers, but exist as mixtures of monomers and dimers in solution.

References

Jan 13, 2010·Chemical Communications : Chem Comm·Scott R Daly, Gregory S Girolami
Jan 30, 2010·Journal of the American Chemical Society·Scott R DalyGregory S Girolami
May 11, 2010·Inorganic Chemistry·Scott R Daly, Gregory S Girolami
Aug 21, 2010·Inorganic Chemistry·Mitchell R AnsteyJoseph G Cordaro
Oct 13, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Keith IzodRoss W Harrington
Jun 7, 2012·Inorganic Chemistry·Scott R DalyGregory S Girolami
Apr 11, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Stephen M MansellPolly L Arnold
Jul 9, 2014·Journal of the American Chemical Society·Polly L ArnoldJason B Love
May 28, 2015·Angewandte Chemie·Justin A BogartEric J Schelter
Aug 8, 2015·Inorganic Chemistry·H BraunschweigM-H Lemée-Cailleau
Dec 14, 2016·Proceedings of the National Academy of Sciences of the United States of America·Justin A BogartEric J Schelter
Feb 22, 2017·Chemical Society Reviews·Mark PaskeviciusTorben R Jensen

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Citations

Dec 24, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Keith IzodWilliam Clegg
Aug 5, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Taylor V Fetrow, Scott R Daly
Jan 25, 2020·Inorganic Chemistry·Judith RiedhammerDaniel J Mindiola

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Methods Mentioned

BETA
X-ray
NMR
XRD

Software Mentioned

Turbomole

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