How is oxygen incorporated into oxides? A comprehensive kinetic study of a simple solid-state reaction with SrTiO3 as a model material

Angewandte Chemie
Rotraut Merkle, Joachim Maier

Abstract

The kinetics of stoichiometry change of an oxide--a prototype of a simple solid-state reaction and a process of substantial technological relevance--is studied and analyzed in great detail. Oxygen incorporation into strontium titanate was chosen as a model process. The complete reaction can be phenomenologically and mechanistically understood beginning with the surface reaction and ending with the transport in the perovskite. Key elements are a detailed knowledge of the defect chemistry of the perovskite as well as the application of a variety of experimental and theoretical tools, many of them evolving from this study. The importance of the reaction and transport steps for (electro)chemical applications is emphasized.

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Citations

Jan 20, 2012·ACS Nano·Jing QiJianlin Liu
Apr 17, 2009·Physical Chemistry Chemical Physics : PCCP·Joachim Maier
May 8, 2010·Physical Chemistry Chemical Physics : PCCP·N LópezS Mathur
Feb 25, 2011·Physical Chemistry Chemical Physics : PCCP·Jianmin ShiKlaus-Dieter Becker
Oct 18, 2011·Physical Chemistry Chemical Physics : PCCP·Christian LenserRegina Dittmann
Aug 2, 2012·Physical Chemistry Chemical Physics : PCCP·Kian KermanShriram Ramanathan
Apr 26, 2013·Physical Chemistry Chemical Physics : PCCP·Annemarie KoehlJacek Szade
Dec 14, 2011·Sensors·Ralf MoosIchiro Matsubara
Jul 28, 2015·Faraday Discussions·Helena TéllezTatsumi Ishihara
Jul 28, 2015·Physical Chemistry Chemical Physics : PCCP·Tor S BjørheimJoachim Maier
Jun 9, 2018·Advanced Materials·Thomas HeisigRegina Dittmann
Jan 17, 2017·Scientific Reports·Felix V E HenslingRegina Dittmann
Aug 9, 2018·Angewandte Chemie·Adam H SlavneyHemamala I Karunadasa
Apr 17, 2009·Physical Chemistry Chemical Physics : PCCP·Chr ArgirusisW Maus-Friedrichs
Apr 28, 2009·Nature Materials·C-H YangR Ramesh
May 1, 2013·Angewandte Chemie·Joachim Maier
Feb 23, 2012·Journal of Physics. Condensed Matter : an Institute of Physics Journal·E BlokhinJ Maier
Aug 13, 2013·Science and Technology of Advanced Materials·Klaus Funke
May 8, 2013·Advanced Materials·Oliver GerbigJoachim Maier
Jan 29, 2013·Angewandte Chemie·Fangyi ChengJun Chen
May 26, 2018·Physical Chemistry Chemical Physics : PCCP·Henning SchraknepperRoger A De Souza
Jun 17, 2016·Reports on Progress in Physics·Seungbum HongDillon D Fong
Oct 11, 2017·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Matthias GrünbacherSimon Penner
Jun 13, 2018·Scientific Reports·F V E HenslingR Dittmann
Feb 23, 2020·Nature Communications·Yuji NoguchiMasaru Miyayama

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