Hydrazine-hydrothermal synthesis and characterization of the two new quaternary thioantimonates(III) BaAgSbS3 and BaAgSbS3·H2O

Inorganic Chemistry
Chang LiuYi Liu

Abstract

The two new quaternary thioantimonates(III) BaAgSbS3 (1) and BaAgSbS3·H2O (2) have been synthesized through a hydrazine-hydrothermal method at low temperature. Compound 1 possesses a two-dimensional (2D) layer structure, while compound 2 features a three-dimensional (3D) channel framework. The optical band gaps of 1 and 2 are approximately 2.2 and 2.4 eV, respectively. Our results clearly indicated that the hydrazine-hydrothermal method could offer exciting opportunities for exploring novel multinary chalcogenides with diverse crystal structures and interesting physical properties.

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Citations

Jan 12, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Yi LiuPingyun Feng
Dec 9, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Hong ChenXin-Tao Wu
Aug 14, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Yanhua LiYonglin An

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