Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst

Chemical Communications : Chem Comm
Hagit Ben-DaatRyan J Trovitch

Abstract

Addition of NaEt3BH to (Ph2PPrDI)CoCl2affords the corresponding monohydride, (Ph2PPrDI)CoH. X-ray diffraction and DFT calculations indicate that this compound possesses a radical monoanion α-DI chelate and a Co(ii) centre. Notably, (Ph2PPrDI)CoH catalyzes the hydroboration of alkynes and dihydroboration of nitriles under mild conditions.

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