Hydrophobic interface controlled electrochemical sensing of nitrite based on one step synthesis of polyhedral oligomeric silsesquioxane/reduced graphene oxide nanocomposite

Talanta
Wushuang BaiJianbin Zheng

Abstract

In this paper, we report a novel hydrophobic interface controlled electrochemical sensing of nitrite based on polyhedral oligomeric silsesquioxane/ reduced graphene oxide nanocomposite (POSS/rGO). The POSS/rGO is prepared by one step hydrothermal synthesis method, and characterized by transmission electron microscopy (TEM), fourier transform infrared spectroscopy (FT-IR), Zeta-potential measurement analyzer, electrochemical impedance spectroscopy (EIS) and zero current potential method respectively. Then the POSS/rGO composite is used to fabricate electrochemical sensor for nitrite detection. According to experimental results, it is found that under control of hydrophobic force, the current peak will be shifted to lower potential (0.72 V) and the possible reason has been analyzed in manuscript. In addition, the POSS/rGO based sensor also has wide linear range (0.5 μM to 120 mM), low detection limit (0.08 μM) and good selectivity. In a word, the hydrophobic force controlled detection in this paper will provide a new platform for electrochemical sensing.

References

Dec 17, 2008·Nano Letters·Yan WangYongsheng Chen
Jun 24, 2010·Nature Chemistry·Akbar BagriVivek B Shenoy
Oct 12, 2010·Science·John R MillerB C Holloway
Nov 26, 2010·Nature Chemistry·Kian Ping LohManish Chhowalla
Apr 29, 2011·Biosensors & Bioelectronics·Xiao-xia GuoJun-feng Song
Feb 23, 2013·ACS Applied Materials & Interfaces·Guoqiang LuoHuogen Yu
Jul 13, 2013·ACS Applied Materials & Interfaces·Jen-Yuan WangKuo-Chuan Ho

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