Hydrophosphination of boron-boron multiple bonds.

Chemical Science
Tom E StennettHolger Braunschweig

Abstract

Five compounds containing boron-boron multiple bonds are shown to undergo hydrophosphination reactions with diphenylphosphine in the absence of a catalyst. With diborenes, the products obtained are highly dependent on the substitution pattern at the boron atoms, with both 1,1- and 1,2-hydrophosphinations observed. With a symmetrical diboryne, 1,2-hydrophosphination yields a hydro(phosphino)diborene. The different mechanistic pathways for the hydrophosphination of diborenes are rationalised with the aid of density functional theory calculations.

References

Oct 24, 2001·Inorganic Chemistry·Tuqiang ChenHeinrich Nöth
Jul 24, 2008·Chemical Society Reviews·Sharonna Greenberg, Douglas W Stephan
Aug 14, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Amor RodriguezGuy Bertrand
Aug 30, 2008·Journal of the American Chemical Society·Stephen J GeierDouglas W Stephan
Dec 4, 2010·Inorganic Chemistry·Stephen J GeierDouglas W Stephan
Apr 7, 2012·Journal of the American Chemical Society·Abderrahmane AmgouneDidier Bourissou
May 15, 2013·Organometallics·Alexander M SpokoynyStephen L Buchwald
Oct 22, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·M KaazD Gudat
Dec 19, 2013·Chemical Communications : Chem Comm·Jonathan A BaileyPaul G Pringle
Feb 21, 2014·Angewandte Chemie·Holger BraunschweigStefan Ullrich
Jul 1, 2014·Inorganic Chemistry·Jonathan A BaileyPaul G Pringle
Jul 6, 2014·Beilstein Journal of Organic Chemistry·Iris WautersChristian V Stevens
Aug 7, 2014·Chemical Communications : Chem Comm·Holger Braunschweig, Christian Hörl
Apr 29, 2015·Chemical Communications : Chem Comm·Rian D DewhurstTodd B Marder
Aug 12, 2015·Angewandte Chemie·J Philipp Wagner, Peter R Schreiner
Mar 31, 2016·Angewandte Chemie·Holger BraunschweigJ Derek Woollins
Oct 26, 2016·Chemistry : a European Journal·Merle ArrowsmithKai Hammond
Nov 20, 2016·Angewandte Chemie·Merle ArrowsmithTom E Stennett
Feb 2, 2018·Chemical Communications : Chem Comm·Artur LikHolger Helten
Feb 17, 2018·Angewandte Chemie·Tom E StennettHolger Braunschweig
Mar 24, 2018·Nature Communications·Julian BöhnkeHolger Braunschweig
Jul 25, 2018·Journal of the American Chemical Society·Julian BöhnkeHolger Braunschweig
Sep 12, 2018·Angewandte Chemie·Tom E StennettHolger Braunschweig
Oct 3, 2018·Angewandte Chemie·Tom E StennettHolger Braunschweig
Oct 13, 2018·Angewandte Chemie·Adam D GormanPaul G Pringle
Feb 6, 2019·Angewandte Chemie·Jonas H MuessigHolger Braunschweig
Jul 31, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Anna OrdyszewskaRafał Grubba
Aug 28, 2019·Journal of the American Chemical Society·Tobias BrücknerHolger Braunschweig
Sep 7, 2019·Chemical Science·Tobias BrücknerHolger Braunschweig

❮ Previous
Next ❯

Citations

Jan 16, 2021·Journal of the American Chemical Society·Jun FanCheuk-Wai So
Oct 16, 2020·Angewandte Chemie·Tobias BrücknerHolger Braunschweig

❮ Previous
Next ❯

Methods Mentioned

BETA
NMR
X-ray

Software Mentioned

DIST

Related Concepts

Related Feeds

Antibodies: Agglutination

Antibody-mediated agglutination is the clumping of cells in the presence of antibody, which binds multiple cells together. This enhances the clearance of pathogens. Find the latest research on antibody-mediated agglutination here.