Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis

Beilstein Journal of Organic Chemistry
Gwendal GrelierPhilippe Dauban

Abstract

Most of the polyvalent organoiodine compounds derive from iodoarenes, which are released in stoichiometric amounts in any reaction mediated by λ3- or λ5-iodanes. In parallel to the development of solid-supported reagents or reactions catalytic in iodine, a third strategy has emerged to address this issue in terms of sustainability. The atom-economy of transformations involving stoichiometric amounts of λ3- or λ5-iodanes, thus, has been improved by designing tandem reactions that allows for incorporating the aryl motif into the products through a subsequent one-pot nucleophilic addition or catalytic coupling reaction. This review summarizes the main achievements reported in this area.

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Citations

Aug 12, 2018·Chemistry : a European Journal·Susana IzquierdoAlexandr Shafir
Sep 1, 2018·Chemistry : a European Journal·Nicola Lucchetti, Ryan Gilmour
Apr 26, 2019·Chemistry : a European Journal·Junliang WuNaohiko Yoshikai
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Aug 28, 2019·Organic Letters·Konrad KepskiWesley J Moran
Jan 5, 2022·Chemical Communications : Chem Comm·Guobi LiJohn D Protasiewicz

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