Impact of Stereo- and Regiochemistry on Energetic Materials

Journal of the American Chemical Society
Lisa M BartonPhil S Baran

Abstract

The synthesis, physical properties, and calculated performances of six stereo- and regioisomeric cyclobutane nitric ester materials are described. While the calculated performances of these isomers, as expected, were similar, their physical properties were found to be extremely different. By alteration of the stereo- and regiochemistry, complete tunability in the form of low- or high-melting solids, stand-alone melt-castable explosives, melt-castable explosive eutectic compounds, and liquid propellant materials was obtained. This demonstrates that theoretical calculations should not be the main factor in driving the design of new materials and that stereo- and regiochemistry matter in the design of compounds of potential relevance to energetic formulators.

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Citations

Aug 11, 2020·ChemistryOpen·Dominique R WozniakDavin G Piercey
Dec 17, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Alexander A LarinNikita V Muravyev
Jan 22, 2021·Angewandte Chemie·Anup BhuniaArmido Studer
Apr 29, 2021·The Journal of Physical Chemistry. a·Dmitry V KhakimovNina N Makhova
Jun 1, 2021·ACS Omega·Jesse J Sabatini, Eric C Johnson
Jun 12, 2021·Inorganic Chemistry·Sebastian R YoccaDavin G Piercey
Jul 23, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Michael S GruhneJörg Stierstorfer
Nov 6, 2020·Organic Letters·Dominique R WozniakDavin G Piercey
Feb 28, 2020·The Journal of Organic Chemistry·Nicholas LeaseVirginia W Manner
Sep 4, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Sicheng LiaoQinghua Zhang

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