Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal-organic framework

Chemical Communications : Chem Comm
Andrey A BezrukovPascal D C Dietzel

Abstract

Two zirconium-organic frameworks were synthesized by exchanging the acetate ligands in [Zr12O8(OH)8(CH3COO)24] with polydentate linkers. Partial substitution of acetate groups by a phosphine based linker yielded a new porous framework with this unique dimeric Zr12cluster unit as molecular building block. More exhaustive substitution of acetate resulted in cleavage of the Zr12unit and formation of UiO-67.

References

Jan 5, 2006·Chemical Communications : Chem Comm·Suzy SurbléGérard Férey
Sep 27, 2008·Journal of the American Chemical Society·Jasmina Hafizovic CavkaKarl Petter Lillerud
Mar 18, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Simon M HumphreyErica R Wise
Jan 21, 2010·Chemical Communications : Chem Comm·Vincent GuillermGérard Férey
Aug 12, 2010·Journal of the American Chemical Society·Steffen HausdorfFlorian O R L Mertens
Jul 18, 2012·Chemical Communications : Chem Comm·Volodymyr BonStefan Kaskel
Sep 14, 2012·ACS Applied Materials & Interfaces·Simona MagginiRosa Di Maggio
Mar 12, 2013·Acta Crystallographica. Section E, Structure Reports Online·Matthias MaerczHelmer Fjellvåg
Mar 12, 2013·Acta Crystallographica. Section E, Structure Reports Online·Matthias MaerczHelmer Fjellvåg
Oct 16, 2013·Journal of the American Chemical Society·Dawei FengHong-Cai Zhou
Oct 24, 2013·Inorganic Chemistry·Dawei FengHong-Cai Zhou
Mar 5, 2014·Journal of the American Chemical Society·Hiroyasu FurukawaOmar M Yaghi
Apr 2, 2014·Journal of the American Chemical Society·Joseph M FalkowskiWenbin Lin
Jun 21, 2014·Chemical Society Reviews·Thomas Devic, Christian Serre
Oct 18, 2014·Chemical Communications : Chem Comm·Marco TaddeiRiccardo Vivani
Feb 26, 2015·Journal of the American Chemical Society·Shuai YuanHong-Cai Zhou
Aug 25, 2015·European Journal of Inorganic Chemistry·Johannes KreutzerUlrich Schubert
Dec 24, 2015·Chemical Communications : Chem Comm·Krunoslav UžarevićTomislav Friščić
Feb 18, 2016·Chemical Society Reviews·Yan BaiHong-Cai Zhou
May 7, 2016·Journal of the American Chemical Society·Shuai YuanHong-Cai Zhou
Jul 28, 2016·Journal of the American Chemical Society·Takahiro SawanoWenbin Lin
Oct 21, 2016·Chemical Communications : Chem Comm·S WaitschatN Stock
Dec 14, 2017·Chemical Communications : Chem Comm·Simon SmoldersDirk E De Vos

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Citations

May 29, 2018·Chemical Communications : Chem Comm·Athena M FidelliKrunoslav UŽarević
Jul 7, 2018·Chemistry : a European Journal·Ram R R PrasadMatthew L Clarke
Feb 15, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Shing Bo PehDan Zhao
Oct 27, 2020·Angewandte Chemie·Saurav BhattacharyaUlrich Kortz
Apr 6, 2020·Chemical Science·Ross S Forgan
Sep 27, 2018·Inorganic Chemistry·Jannick JacobsenNorbert Stock
Nov 19, 2019·ACS Applied Materials & Interfaces·Fengxiang ZhouQingyuan Yang

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Methods Mentioned

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