Induction, control, and rationalization of supramolecular chirogenesis using metalloporphyrin tweezers: a structure-function correlation.

Dalton Transactions : an International Journal of Inorganic Chemistry
Avinash DhamijaSankar Prasad Rath

Abstract

Supramolecular chirogenesis is one of the most rudimentary topics in the interdisciplinary sciences and essentially deals with various natural processes and innovative modern technologies. A comprehensive and rigorous understanding of such phenomenon is necessary to have a clear insight into the fundamental mechanisms and the various controlling factors, which would eventually lead to a range of practical applications of chiral supramolecular science. Metalloporphyrin tweezers have been extensively employed for such chirogenic processes due to their exciting physicochemical and tunable spectral properties, large stabilities, easily available synthetic protocols, and excellent abilities to form molecular assemblies. During the last few decades, various metalloporphyrin tweezers have been developed and considerably utilized by several research groups for assigning the absolute configuration to a variety of chiral diamines, conjugates of primary and secondary amines, amino alcohols, secondary alcohols, α-chiral carboxylic acids, etc. Our group has been at the forefront in trying to establish the structure-property correlation in this important area of interdisciplinary research. A brief account of our systematic investigation for ...Continue Reading

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Citations

Sep 14, 2021·ACS Omega·Sruti MondalSanjib Kar

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Methods Mentioned

BETA
circular dichroism
X-ray

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