Influence of polaron doping and concentration dependent FRET on luminescence of PAni-PMMA blends for application in PLEDs

Physical Chemistry Chemical Physics : PCCP
Dhritiman Banerjee, Asit Kumar Kar

Abstract

The role of quantum mechanical phenomena such as polaron-exciton quenching interaction and concentration-dependent FRET in determining the luminescence efficiency of PAni-PMMA polymer blends has been investigated. PAni samples prepared in different environments using different acids and bases show different absorbance and emission profiles indicating a direct relation between generated polarons in PAni by acid-base doping-dedoping and photoluminescence spectra of PAni. The observed low luminescence in PAni has been modeled using exciton quenching by polarons through charge transfer. The investigation also reveals that the effect of exciton quenching by polarons becomes pronounced when the polaron concentration in PAni reaches a density of ∼1017-1018 polarons cm-3. To overcome the low emission efficiency of PAni, poly(methyl methacrylate) (PMMA) has been blended with PAni. The blending of donor PMMA (D) with acceptor PAni (A) gives rise to another quantum phenomenon - donor PMMA concentration dependent FRET between PAni (A) and PMMA (D). It is experimentally observed from the photoluminescence measurements of blends that at high donor PMMA concentration above a critical value in the PAni-PMMA polymer blend the emission profile o...Continue Reading

References

Mar 30, 2002·Science·Wendy U HuynhA Paul Alivisatos
May 10, 2002·Journal of Biotechnology·B W van der Meer
Sep 24, 2004·Journal of the American Chemical Society·Xavier CrispinWilliam R Salaneck
Jan 11, 2005·Nature Materials·Steven A McDonaldEdward H Sargent
May 12, 2006·The Journal of Physical Chemistry. B·Miroslava TrchováGordana Cirić-Marjanović
Jul 21, 2006·The Journal of Physical Chemistry. B·Sander F WuisterAndries Meijerink
Jan 31, 2008·Chemical Reviews·Sergey M Borisov, Otto S Wolfbeis
Apr 23, 2017·Polymers·Thanh-Hai LeHyeonseok Yoon

❮ Previous
Next ❯

Methods Mentioned

BETA
FRET
Fluorescence

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.