Influence of sulfamethazine (SMT) on the adsorption of antimony by the black soil: Implication for the complexation between SMT and antimony

The Science of the Total Environment
Yurui FanChi He

Abstract

This paper reported when sulfamethazine (SMT) and antimony (Sb(V)) coexisted in aqueous solution at pH of 3.0, 5.0 and 7.0, the complexation between SMT and Sb(V) occurred. Such a complexation impeded the adsorption of Sb(V) on the black soil. The higher the solution pH value was, the more the amount of Sb(V) was prevented from adsorbing on the black soil. The maximum adsorption capacity (qm) of Sb(V) at the presence of SMT under pH of 3.0, 5.0 and 7.0 was 5.28, 3.45 and 1.95 mg/g, respectively. -NH2, NH, SO and CN of pyrimidine ring carried by SMT acted as the complexation sites with Sb(V). The complexation constant K were - 3.15, -3.26 and - 3.48 at pH of 7.0, 5.0 and 3.0, respectively, indicating that the complexation strength between SMT and Sb(V) followed the order of pH 7.0 > pH 5.0 > pH 3.0. The binding energy between Sb(V) and the CN group of pyrimidine ring was the highest (1.42 eV), and then followed by the groups of -NH (1.37 eV), SO (0.66 eV) and -NH2 (0.39 eV). Besides SO and CN, Sb(V) tends to complex with NH via coordination bond at pH of 7.0 while -NH2 via cation-π interaction at pH 3.0 and 5.0. Compared to pH of 5.0, the strength of cation-π interaction at pH of 3.0 weakened according to the molecular electrost...Continue Reading

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Citations

Sep 18, 2021·Environmental Science and Pollution Research International·José Arnaldo Santana CostaCaio Marcio Paranhos

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