Influence of water content on the self-assembly of metal-organic frameworks based on pyridine-3,5-dicarboxylate

Inorganic Chemistry
Yi-Long LuKuang-Lieh Lu

Abstract

A 0D discrete molecule [Co(3,5-pdc)(H2O)5].2H2O (1) was obtained in quantitative yield from the reaction of CoCl2.6H2O and pyridine-3,5-dicarboxylate (3,5-pdc) in pure water solvent at ambient temperature. While a 1D zigzag chain species, [{Co(3,5-pdc)(H2O)4}.H2O]n (2), was produced in a water-rich environment, a 2D layer compound, [Co(3,5-pdc)(H2O)2]n (3), with a 6(3) topology was generated under a water-reduced condition and a 2D sheet structure, [{Cu(3,5-pdc)(py)2}.H2O.EtOH]n (4), was formed under a water-poor condition. Compounds 1, 2, and 4 were characterized by single-crystal X-ray diffraction analysis. The 1D zigzag chain 2 shows a recoverable collapsing property. Compound 4 adopts a 2D sheet structure with a 4.8(2) topology, observed for the first time for the 3,5-pdc-related metal-organic frameworks. Water content was found to be an important factor in determining the topologies of the products in the self-assembly of divalent metal ions (Co2+, Cu2+) and pyridine-3,5-dicarboxylate under mild conditions.

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Citations

Sep 14, 2007·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Gene-Hsiang Lee, Hsin-Ta Wang
May 6, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Hailong FeiWenjing Feng
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Jul 5, 2016·Acta Crystallographica. Section E, Crystallographic Communications·Cheng-Chen ShenLei Han
Aug 20, 2021·Inorganic Chemistry·Xinxin HangHuan Pang

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