Infrared spectrum of nitrobenzene anion in solid argon

The Journal of Physical Chemistry. a
Renhu MaMingfei Zhou

Abstract

The infrared spectrum of the nitrobenzene anion isolated in solid argon is presented. The nitrobenzene anion was prepared by co-deposition of a nitrobenzene/Ar mixture with high-frequency discharged argon at 4 K. Photosensitive absorptions are assigned to different vibrational modes of the nitrobenzene anion on the basis of isotopic substitutions ((15)N and deuterium), as well as theoretical calculations. The anion loses one electron to give the neutral nitrobenzene upon visible light (500 < lambda < 600 nm) irradiation. Theoretical calculations predicated that the anion has a planar C(2v) symmetry with a shorter C-N bond and longer N-O bonds relative to those of neutral nitrobenzene.

References

Jul 13, 2006·The Journal of Physical Chemistry. a·Rongjing YangMingfei Zhou

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Citations

Sep 30, 2016·The Journal of Physical Chemistry Letters·Han-Kyu ChoiZee Hwan Kim
Nov 13, 2009·The Journal of Physical Chemistry. a·Renhu MaMingfei Zhou
Apr 1, 2009·The Journal of Physical Chemistry. a·Renhu MaLester Andrews

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