Infrared Study of Substituted Acetophenones Adsorbed on Silica

Journal of Colloid and Interface Science
I AhmadC H Rochester

Abstract

Infrared spectra are reported of silica preheated at 873 K and exposed at 295 K to the vapors of four acetophenones (H, 4-Me, 4-OMe, and 4-NO2). Surface-adsorbate interactions involved hydrogen bonding between isolated silanol groups and carbonyl groups, the strength of the hydrogen bonds being related to the electronic effects of the acetophenone ring substituents. The 4-OMe compound also generated SiOH···OMe hydrogen bonds probably via a bridging structure involving two silanol groups perturbed simultaneously by each adsorbed molecule. The mode of adsorption of substituted benzene derivatives on silica is strongly dependent on the electronic effects of the substituents on each other and on the aromatic pi-electron charge density. Copyright 1997 Academic Press. Copyright 1997Academic Press

Citations

Aug 2, 2006·Advances in Colloid and Interface Science·Sudam K ParidaB K Mishra
Oct 30, 1998·Journal of Colloid and Interface Science·I AhmadC H Rochester

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