Abstract
This study assessed personal exposure to 1,3-butadiene (BD) and styrene in three plants manufacturing styrene-butadiene (SB) copolymers. Air samples were collected from the breathing zone of 28 workers over 4 months in three SB plants using diffusive samplers. The total number of samples was 885 with the number of samples per participant varying from 19 to 39. Samples were collected by use of 3M 3500 passive monitors and analyzed with a gas chromatograph (GC). Sampling proved to be simple and inexpensive and laboratory analysis of BD could detect 0.01 and 0.007 part per millions (ppm) of styrene in the 8h samples. In the case of BD, 624 samples were below the limit of quantification (LOQ), 240 samples were between the LOQ and 1 ppm, and 21 samples exceeded the threshold limit value (TLV). In the case of styrene 336 samples were below the LOQ, 548 samples were between the LOQ and 20 ppm. The TLV was exceeded once. The data gives a comprehensive picture of personal exposure of workers in modern SB latex manufacturing plants. The study illustrates also how the new TLV of BD is being implemented.
References
Oct 1, 1992·American Journal of Epidemiology·C Santos-BurgoaL Schwartz
Jun 1, 1990·Environmental Health Perspectives·R A LemenD P Brown
Jun 1, 1990·Environmental Health Perspectives·P J Landrigan
Jun 1, 1990·Environmental Health Perspectives·N L Morrow
Jun 1, 1990·Environmental Health Perspectives·G M MatanoskiL Schwartz
Jun 1, 1990·Environmental Health Perspectives·J M FajenE R Krishnan
Dec 1, 1983·Journal of Applied Toxicology : JAT·J E Amoore, E Hautala
Dec 1, 1982·Scandinavian Journal of Work, Environment & Health·T J MeinhardtR J Young
Jun 1, 1995·Environmental Health Perspectives·E M WardC A Fessler-Flesch
Jan 1, 1994·Critical Reviews in Toxicology·R R MillerA Poole
Jan 1, 1994·International Archives of Occupational and Environmental Health·H CheckowayL G Costa
Jan 1, 1996·Mutagenesis·M SorsaS Osterman-Golkar
Mar 1, 1996·Mutagenesis·S Osterman-GolkarM Sorsa
Mar 11, 2000·Occupational and Environmental Medicine·T KauppinenM Kogevinas
Jun 9, 2001·Chemico-biological Interactions·J Lynch
Jun 9, 2001·Chemico-biological Interactions·G J DollardM E Jenkin
Jun 9, 2001·Chemico-biological Interactions·J Lynch
Jun 9, 2001·Chemico-biological Interactions·R B HayesM T Smith
Jun 9, 2001·Chemico-biological Interactions·J A Bond, M A Medinsky
Feb 28, 2003·Environmental and Molecular Mutagenesis·Sherif Z Abdel-RahmanJonathan B Ward
Mar 5, 2004·International Archives of Occupational and Environmental Health·Tiina Anttinen-KlemettiKimmo Peltonen
Citations
Jul 17, 2010·The Journal of Chemical Physics·A HanfR K Vatsa
Dec 23, 2011·Drug and Chemical Toxicology·Constantinos PistosSotiris Athanaselis
Oct 16, 2007·Analytica Chimica Acta·Agata Kot-WasikJacek Namieśnik
Aug 19, 2007·Toxicology in Vitro : an International Journal Published in Association with BIBRA·Sridevi YadavilliPerpetua M Muganda
Nov 8, 2008·Cancer Epidemiology, Biomarkers & Prevention : a Publication of the American Association for Cancer Research, Cosponsored by the American Society of Preventive Oncology·Alessandra PrimaveraMario Lo Bello
Jul 19, 2008·The Journal of Physical Chemistry. a·Deepali VimalPhilip S Stevens