Insertion of a Cationic Metallogermylene into E-H Bonds (E = H, B, Si)

Journal of the American Chemical Society
Koya InomataHiromi Tobita

Abstract

A cationic germylene containing tungsten and N-heterocyclic carbene units reacted with H2 in fluorobenzene at 60 °C, resulting in its insertion into the H-H bond. It also activated the Si-H bond of ethyldimethylsilane and the B-H bond of pinacolborane at ambient temperature to give the insertion products. The latter insertion reactions against hydrosilane and hydroborane were found to be reversible.

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Citations

Dec 23, 2016·Angewandte Chemie·Natalia Del RioTsuyoshi Kato
Nov 15, 2017·Chemical Communications : Chem Comm·Martin M JuckelCameron Jones
Aug 10, 2016·Angewandte Chemie·Tatsumi OchiaiShigeyoshi Inoue
May 23, 2018·Chemistry : a European Journal·Masayuku NakagakiShigeyoshi Sakaki
Jun 22, 2019·Physical Chemistry Chemical Physics : PCCP·Shailja Jain, Kumar Vanka
Oct 30, 2019·Chemistry : a European Journal·Robert J ManganSimon Aldridge
Jul 2, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Xueer ZhouSimon Aldridge
Nov 5, 2016·Angewandte Chemie·Ricardo RodriguezTsuyoshi Kato
Jul 26, 2019·Chemical Science·Matthew M D RoyEric Rivard
Nov 20, 2016·Angewandte Chemie·Zhaowen DongThomas Müller
Feb 23, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Sen-Yu ZhangWei Huang
Apr 14, 2021·Chemistry : a European Journal·Matthew M D RoyEric Rivard
Jun 26, 2021·Chemistry : a European Journal·Debotra SarkarShigeyoshi Inoue
Jan 30, 2018·Journal of the American Chemical Society·Zhaowen DongThomas Müller
Mar 21, 2018·Chemical Reviews·Terry Chu, Georgii I Nikonov
Jul 4, 2018·Chemical Reviews·Vitaly NesterovShigeyoshi Inoue
Nov 22, 2017·Inorganic Chemistry·Nemanja ĐorđevićDragoslav Vidović
Dec 16, 2016·Inorganic Chemistry·Christian P SindlingerLars Wesemann
Jun 8, 2017·Journal of the American Chemical Society·Daniel WendelBernhard Rieger
Oct 7, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Marcel SchorppIngo Krossing
Oct 7, 2021·Chemistry : a European Journal·Sonia BajoJesús Campos

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