Insertion of CO2 into the carbon-boron bond of a boronic ester ligand

Chemical Communications : Chem Comm
Trevor JanesDatong Song

Abstract

New Ru and Zn diazafluorenyl complexes undergo C-H borylation of the diazafluorenyl ligand to form the corresponding diazafluorenylboronic ester complexes, which can insert CO2 into their C-B bonds to form boryl ester functionalities. The relevance of these new reactivities towards catalytic CO2 reduction has also been explored.

References

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Mar 21, 2015·Chemical Communications : Chem Comm·Marc-André CourtemancheFrédéric-Georges Fontaine
Apr 15, 2015·Journal of the American Chemical Society·Zhenpin LuHermann A Wegner
Jun 18, 2015·Chemical Communications : Chem Comm·Yanxin YangDatong Song
Jul 24, 2015·Journal of the American Chemical Society·Guanghua JinSébastien Bontemps
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Citations

Dec 14, 2016·Topics in Current Chemistry·Xiao-Feng Wu, Feng Zheng
Jun 12, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Sem Raj Tamang, Michael Findlater
Jun 2, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiaoming WangXin Xu
Nov 20, 2016·Angewandte Chemie·Samaresh Chandra SauSwadhin K Mandal
Aug 3, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Stephen J GeierStephen A Westcott
Oct 4, 2017·Chemical Communications : Chem Comm·Trevor JanesDatong Song
Mar 2, 2018·Inorganic Chemistry·Longfei LiMing Lei
Jan 11, 2022·Chemistry : a European Journal·Wade C HenkeJames D Blakemore

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