PMID: 11909064Mar 23, 2002Paper

Inside the hysteresis loop: multiplicity of internal states in confined fluids

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
Alexander V NeimarkAleksey Vishnyakov

Abstract

We study the equilibrium and stability of metastable states and capillary condensation hysteresis of a Lennard-Jones fluid in cylindrical pores by means of the canonical ensemble density functional theory and gauge cell Monte Carlo simulations. We demonstrate a possibility for the existence of multiple laterally uniform internal states of equal density inside the hysteresis loop. The region of multiple states is bounded by the states of zero compressibility. The internal states can be stabilized in Monte Carlo simulations constraining the density fluctuations.

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Citations

Dec 14, 2011·The Journal of Chemical Physics·Christopher J RasmussenAlexander V Neimark
Oct 16, 2012·The Journal of Chemical Physics·Christopher J RasmussenAlexander V Neimark
Dec 3, 2008·The Journal of Chemical Physics·Gersh O Berim, Eli Ruckenstein
Feb 5, 2009·The Journal of Chemical Physics·Gersh O Berim, Eli Ruckenstein
Feb 10, 2011·The Journal of Chemical Physics·Jürn W P Schmelzer, Alexander S Abyzov
Jul 16, 2008·The Journal of Chemical Physics·Gersh O Berim, Eli Ruckenstein
Jul 13, 2005·The Journal of Chemical Physics·Alexander V Neimark, Aleksey Vishnyakov
Nov 18, 2011·The Journal of Chemical Physics·Yawei LiuXianren Zhang
Jan 22, 2008·The Journal of Chemical Physics·Gersh O Berim, Eli Ruckenstein
Apr 10, 2008·The Journal of Chemical Physics·Gersh O Berim, Eli Ruckenstein
Oct 2, 2009·The Journal of Chemical Physics·Joël PuibassetGilles Tarjus
Aug 26, 2014·The Journal of Chemical Physics·Øivind WilhelmsenDavid Reguera
Feb 16, 2015·The Journal of Chemical Physics·Øivind Wilhelmsen, David Reguera
Oct 16, 2004·The Journal of Chemical Physics·B Husowitz, V Talanquer
Jun 11, 2019·Physical Chemistry Chemical Physics : PCCP·Gersh O Berim, Eli Ruckenstein
Jul 30, 2019·Physical Chemistry Chemical Physics : PCCP·Gersh O Berim, Eli Ruckenstein
May 8, 2009·Physical Chemistry Chemical Physics : PCCP·Rustem ValiullinRoger Gläser
Sep 15, 2016·Physical Review. E·Markus GrossS Dietrich
Jul 23, 2008·Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics·Zhikuan FengWenchuan Wang
Dec 31, 2005·Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics·Silvina M Gatica, Milton W Cole
Jun 13, 2009·Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics·Yumei MenWenchuan Wang
Mar 17, 2011·Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics·Gersh O Berim, Eli Ruckenstein
Mar 30, 2010·The Journal of Physical Chemistry. B·Piotr KowalczykArtur P Terzyk
Jun 5, 2008·Langmuir : the ACS Journal of Surfaces and Colloids·Piotr KowalczykAlexander V Neimark
Mar 10, 2010·Langmuir : the ACS Journal of Surfaces and Colloids·Christopher J RasmussenAlexander V Neimark
Apr 3, 2008·Langmuir : the ACS Journal of Surfaces and Colloids·Fengxian ZhengWenchuan Wang
Feb 9, 2011·Journal of the American Chemical Society·Filipe FurtadoJörg Kärger
Jul 25, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Gennady Yu GorAlexander V Neimark
May 17, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Gennady Yu Gor, Alexander V Neimark
Apr 27, 2013·The Journal of Physical Chemistry. B·Salvador A Sartarelli, Leszek Szybisz
Aug 24, 2005·Langmuir : the ACS Journal of Surfaces and Colloids·G A TompsettW C Conner
Jul 21, 2006·The Journal of Physical Chemistry. B·Piotr KowalczykKatsumi Kaneko
Jul 21, 2006·The Journal of Physical Chemistry. B·Alexander V Neimark, Aleksey Vishnyakov

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