Integration of Enzymatic and Heterogeneous Catalysis for One-Pot Production of Fructose from Glucose

ChemSusChem
Jiankui SunGuoyong Song

Abstract

The search for efficient routes for the production of fructose from biomass-derived glucose is of great interest and importance, as fructose is a highly attractive substrate in the conversion of cellulosic biomass into biofuels and chemicals. In this study, a one-pot, multistep procedure involving enzyme-catalyzed oxidation of glucose at C2 and Ni/C-catalyzed hydrogenation of d-glucosone at C1 selectively gives fructose in 77 % yield. Starting from upstream substrates such as α-cellulose and starch, fructose was also generated with similar efficiency and selectivity by the combination of enzymatic and heterogeneous catalysis. This method constitutes a new means of preparing fructose from biomass-derived substrates in an efficient fashion.

References

Mar 1, 1990·Applied Biochemistry and Biotechnology·Y B Tewari
Feb 1, 1990·Proceedings of the National Academy of Sciences of the United States of America·C A Collyer, D M Blow
Nov 1, 1993·The American Journal of Clinical Nutrition·L M Hanover, J S White
Jan 1, 1988·Physical Review A: General Physics·V N RajaC Bahr
Feb 6, 2003·Journal of Agricultural and Food Chemistry·Eleni PapantoniouJ David Schofield
Jun 22, 2007·Nature·Yuriy Román-LeshkovJames A Dumesic
Mar 21, 2008·Carbohydrate Research·K Buchholz, J Seibel
Jan 23, 2009·Journal of the American Chemical Society·Joseph B Binder, Ronald T Raines
Mar 24, 2010·Proceedings of the National Academy of Sciences of the United States of America·Manuel MolinerMark E Davis
Sep 28, 2010·Applied Biochemistry and Biotechnology·Amin Karmali, José Coelho
Oct 22, 2010·Angewandte Chemie·Yuriy Román-LeshkovMark E Davis
Jun 6, 2012·Proceedings of the National Academy of Sciences of the United States of America·Ricardo Bermejo-DevalMark E Davis
Feb 12, 2013·Chemical Reviews·Robert-Jan van PuttenJohannes G de Vries
Mar 20, 2013·Journal of the American Chemical Society·Shunmugavel SaravanamuruganAnders Riisager
Oct 20, 2015·Chemical Communications : Chem Comm·Jiechen KongChen Zhao
Mar 8, 2016·ChemSusChem·Irina Delidovich, Regina Palkovits
Mar 15, 2016·Organic Letters·Xuefeng TanXumu Zhang
Apr 4, 2017·Current Opinion in Biotechnology·Ian WheeldonHarvey Blanch

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