Intensely luminescent gold(I)-silver(I) cluster with hypercoordinated carbon

Journal of the American Chemical Society
Jian-Hua Jia, Quan-Ming Wang

Abstract

Intense solution and solid state phosphorescence was observed on a novel photostable gold(I)-silver(I) cluster with hypercoordinated carbon, [Au(6)Ag(2)(C)(dppy)(6)](BF(4))(4), which has a core structure of a hexagold(I) octahedron with two silver(I) atoms capping on a pair of its faces; the incorporation of silver atoms enhances the rigidity and integrity of the cluster.

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Citations

Mar 23, 2013·Inorganic Chemistry·Igor O KoshevoyTapani A Pakkanen
Apr 16, 2013·Journal of the American Chemical Society·Xiao-Li PeiQuan-Ming Wang
Oct 2, 2013·Journal of the American Chemical Society·Yang YangQuan-Ming Wang
Sep 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Igor O KoshevoyTapani A Pakkanen
Mar 17, 2011·Chemical Communications : Chem Comm·Jian-Hua JiaQuan-Ming Wang
Apr 8, 2011·Chemical Communications : Chem Comm·Igor O KoshevoyTapani A Pakkanen
Jul 12, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Igor O KoshevoyTapani A Pakkanen
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Feb 22, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhen LeiQuan-Ming Wang
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