Interaction of anhydride and carboxylic acid compounds with aluminum oxide surfaces studied using infrared reflection absorption spectroscopy

Langmuir : the ACS Journal of Surfaces and Colloids
J van den BrandJ H W de Wit

Abstract

The chemical bonding of three different anhydride and carboxylic acid based compounds with a set of differently prepared aluminum substrates has been investigated using infrared reflection absorption spectroscopy. The compounds were selected to model typically used adhesives, coatings, and self-assembling monolayers. The purpose of the investigation was to study the interaction of these functional groups with the aluminum oxide surface and to determine whether this interaction is influenced by the changes in chemistry and composition of the oxide layer. The extent to which the compounds resisted disbondment in water was also investigated. The oxide layers on the differently prepared substrates were all found to be capable of hydrolysis of the anhydride group, resulting in the formation of two carboxylic acid groups. Subsequently, both of the carboxylic acid groups became deprotonated, to form a coordinatively bonded carboxylate species. The same behavior was also observed for monofunctional carboxylic acids. For all different oxides layers, the carboxylate was found to be coordinated in a bridging bidentate way to two aluminum cations in the oxide layer. The oxide layers showed however clear differences in the amount of molecul...Continue Reading

References

Dec 17, 1997·Journal of Colloid and Interface Science·E McCafferty, J P Wightman

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Citations

Apr 15, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Michael MaxischGuido Grundmeier
Oct 6, 2011·Physical Chemistry Chemical Physics : PCCP·Shuai TanChristopher T Williams
May 1, 2013·Physical Chemistry Chemical Physics : PCCP·J Landoulsi, V Dupres
Feb 14, 2014·Langmuir : the ACS Journal of Surfaces and Colloids·Irma LiascukieneJessem Landoulsi
Jul 27, 2014·Materials Science & Engineering. C, Materials for Biological Applications·Jelena JanićijevićJela Milić
Nov 26, 2014·Langmuir : the ACS Journal of Surfaces and Colloids·Jianhua SunXiaoya Liu
Dec 8, 2014·Journal of Colloid and Interface Science·Jiangyou LongPeixun Fan
Feb 23, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Irma LiascukieneJean-François Lambert
Jan 17, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Tom HauffmanHerman Terryn
Feb 14, 2017·Physical Chemistry Chemical Physics : PCCP·Maayan MatmorNurit Ashkenasy
Apr 6, 2017·Scientific Reports·Bekir Sami YilbasNasser Al-Aqeeli
May 26, 2018·Physical Chemistry Chemical Physics : PCCP·Xiaoyan GaoYong Liu
Nov 1, 2008·Langmuir : the ACS Journal of Surfaces and Colloids·Tom HauffmanHerman Terryn
Jul 26, 2006·The Journal of Physical Chemistry. B·Thomas KrügerThomas Frauenheim
Jul 18, 2008·Langmuir : the ACS Journal of Surfaces and Colloids·M GizaG Grundmeier
Dec 31, 2009·Langmuir : the ACS Journal of Surfaces and Colloids·Aparna RamanEllen S Gawalt
Oct 28, 2008·Langmuir : the ACS Journal of Surfaces and Colloids·V M Bermudez
Dec 10, 2019·ACS Applied Materials & Interfaces·Wei GuLiwei Chen
Nov 2, 2007·Journal of the American Chemical Society·Xiaohang ZhangPeng Xiong

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