Intrinsic broad-band white-light emission by a tuned, corrugated metal-organic framework

Journal of the American Chemical Society
Dorina F SavaTina M Nenoff

Abstract

Herein we report on the broad-band direct white-light originating from a single component emitter, namely a novel three-periodic metal-organic framework (MOF). This material features an unprecedented topology with (3,4)-connected nodes. The structure-function relationship in this system is driven by two complementary unique structural features: corrugation and interpenetration. Good correlation between simulated and experimental emission spectra has been attained, resulting in optimized color properties that approach requirements for solid-state lighting (SSL). Guided by the optimized calculated spectra, the tunability of the assembly was proven by the successful in-framework co-doping of Eu(3+). This resulted in significantly improved color properties, opening new paths for the rational design of alternative materials for SSL applications.

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Citations

May 28, 2013·Chemical Reviews·Valentin Valtchev, Lubomira Tosheva
Jun 17, 2014·Scientific Reports·Pin-Chun ShenChing-Fuh Lin
Mar 21, 2017·Physical Chemistry Chemical Physics : PCCP·Nana Sun, Bing Yan
Jan 23, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Wenyan DanYaming Zhou
Jan 18, 2017·Chemical Communications : Chem Comm·Xiaogang Yang, Dongpeng Yan
Mar 23, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Yongqiang HanGuangming Li
Mar 24, 2017·Angewandte Chemie·Allison M RiceNatalia B Shustova
Jun 15, 2017·ACS Applied Materials & Interfaces·Dorina F Sava GallisKarena W Chapman
Jan 5, 2016·Chemical Communications : Chem Comm·You Zhou, Bing Yan
Jan 7, 2016·Chemical Communications : Chem Comm·Wei XieYa-Qian Lan
Nov 14, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Tatiana N SevastianovaAlexey Y Timoshkin
May 8, 2014·Chemical Society Reviews·Paolo FalcaroMark J Styles
Jun 22, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Qianqian Guo, Ulli Englert
May 9, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Jun ChenGuo-Cong Guo
Apr 7, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Hai-Bing XuMing-Hua Zeng
Feb 2, 2018·Advanced Materials·Jina HaoBing Yan
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Jun 14, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Hui LiXin Liu
May 2, 2018·Chemistry : a European Journal·Xianfeng LiJunhua Luo
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Jul 6, 2012·Angewandte Chemie·Paolo Falcaro, Shuhei Furukawa

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