Investigation of the primary photodynamics of the aqueous formate anion

The Journal of Physical Chemistry. a
Christian PetersenSøren Keiding

Abstract

We have investigated the primary photodynamics of the aqueous formate anion using femtosecond transient absorption spectroscopy. The formate anions are excited at 200 nm, and the resulting products are probed in the region 200-650 nm. The ultraviolet part of the transient spectrum compares favorably with that of O-(aq). However, its counter radical, HCO(aq), is not observed. In the visible region hydrated electrons are observed. The electrons are produced from photodetachment of the formate anions and from two-photon ionization of water.

References

Aug 21, 2002·Origins of Life and Evolution of the Biosphere : the Journal of the International Society for the Study of the Origin of Life·Alain Jorissen, Corinne Cerf

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Citations

Aug 20, 2014·The Journal of Chemical Physics·Ane Riis GadegaardSøren Rud Keiding
Jun 22, 2010·Physical Chemistry Chemical Physics : PCCP·Svend Knak JensenJan Thøgersen
Mar 23, 2019·Physical Chemistry Chemical Physics : PCCP·Marlene Møller MadsenJan Thøgersen
Mar 7, 2008·The Journal of Physical Chemistry. a·Christian PetersenSøren Rud Keiding
Oct 18, 2007·The Journal of Physical Chemistry. a·Christian PetersenSøren R Keiding

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