Investigation of the terahertz vibrational modes of ZIF-8 and ZIF-90 with terahertz time-domain spectroscopy

Chemical Communications : Chem Comm
Nicholas Y TanJ Axel Zeitler

Abstract

We present experimental and computational evidence that gate-opening modes for zeolitic imidazole frameworks can be observed at terahertz frequencies. Our work highlights the critical importance to correctly optimise the crystal structure prior to computational lattice dynamics analysis. The results support the hypothesis that the low energy vibrational modes do indeed play a significant role in host-guest interactions for ZIFs, such as gas loading.

References

Sep 18, 2004·Journal of Computational Chemistry·C M Zicovich-WilsonR Dovesi
Apr 28, 2006·The Journal of Physical Chemistry. B·David Fairén-JiménezCarlos Moreno-Castilla
Jun 27, 2006·Proceedings of the National Academy of Sciences of the United States of America·Kyo Sung ParkOmar M Yaghi
Dec 21, 2007·Proceedings of the National Academy of Sciences of the United States of America·Simon EbbinghausMartina Havenith
Feb 26, 2009·Angewandte Chemie·Jian ZhangXianhui Bu
Apr 16, 2009·Journal of the American Chemical Society·Tao WuPingyun Feng
Jul 30, 2009·Journal of the American Chemical Society·Hai-Long JiangQiang Xu
Sep 3, 2009·Journal of the American Chemical Society·Kunhao LiJing Li
Nov 3, 2009·Accounts of Chemical Research·Anh PhanOmar M Yaghi
Aug 28, 2010·Langmuir : the ACS Journal of Surfaces and Colloids·David Fairen-JimenezTina Düren
May 11, 2011·Journal of the American Chemical Society·D Fairen-JimenezT Düren
Mar 15, 2013·Chemical Communications : Chem Comm·Ke ZhangRonald R Chance
Jun 19, 2013·Physical Chemistry Chemical Physics : PCCP·Juraj SibikJ Axel Zeitler
Jul 9, 2013·Chemistry : a European Journal·Fa-Kuen ShiehKevin C-W Wu
Mar 4, 2014·Molecular Pharmaceutics·Juraj SibikJ Axel Zeitler
Dec 17, 2014·Applied Spectroscopy·Edward P J Parrott, J Axel Zeitler
Jan 24, 2015·Molecular Pharmaceutics·Nicholas Y Tan, J Axel Zeitler

❮ Previous
Next ❯

Citations

Oct 2, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Matthew R Ryder, Jin-Chong Tan
Jul 18, 2016·Biochimica Et Biophysica Acta·Nan JiangAntje Willuweit
Mar 8, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Tian TianDavid Fairen-Jimenez
Jun 29, 2017·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·François-Xavier Coudert
Feb 5, 2016·Chemical Communications : Chem Comm·M E CascoJ Silvestre-Albero
Nov 29, 2017·Physical Chemistry Chemical Physics : PCCP·Alexander KrylovEvgenia Slyusareva
Mar 6, 2019·Nanomaterials·Adrian Gonzalez-NelsonMonique A van der Veen
Aug 7, 2020·The Analyst·Zhongjie ZhuHongwei Zhao
Jun 9, 2020·Journal of Colloid and Interface Science·Filip FormalikBogdan Kuchta
Jun 11, 2019·Journal of the American Chemical Society·Brian PattengaleCharles A Schmuttenmaer
Dec 12, 2017·Journal of the American Chemical Society·Claire L HobdayStephen A Moggach

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

© 2021 Meta ULC. All rights reserved