Ion Selectivity in Nonpolymeric Thermosensitive Systems Induced by Water-Attenuated Supramolecular Recognition

Chemistry : a European Journal
Zhenhui QiShengyi Dong

Abstract

The chemistry of aqueous salt solutions is rich with ambiguities, especially in stimuli-responsive supramolecular systems. Rational use of ion specificity to design supramolecular responsive materials, however, remains a challenging task. In this work, a low-molecular-weight supramolecular system was developed that was used to reveal the underlying systematic relationship between ions, water, and solutes. By utilizing these water-attenuated supramolecular forces (with Kaonly ca. 30 m-1), an alternative concept for fabricating an aqueous responsive system in ionic medium was demonstrated. This work not only provides mechanistic insight into the underdeveloped role of topology in ion specificity upon noncharged polar surfaces, but also demonstrates the feasibility of utilizing weak supramolecular approaches to control the thermoresponsiveness.

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Citations

Jan 24, 2019·Macromolecular Rapid Communications·Yan GeZhenhui Qi
Mar 16, 2019·Beilstein Journal of Organic Chemistry·Yan DengShengyi Dong
Jul 12, 2019·Beilstein Journal of Organic Chemistry·Xin ShenZhenhui Qi
Aug 1, 2021·The Journal of Physical Chemistry Letters·Tiezheng PanZhenhui Qi
May 22, 2020·Organic Letters·Doudou LiPeter J Stang
May 9, 2019·Journal of the American Chemical Society·Qiao ZhangPeter J Stang
Aug 18, 2020·ACS Applied Materials & Interfaces·Tao LiPeter J Stang

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