Ion-transfer voltammetry at a polarized room-temperature molten salt/water interface

Analytical Sciences : the International Journal of the Japan Society for Analytical Chemistry
Hajime Katano, Hirosuke Tatsumi

Abstract

Tetraoctylammonium cation forms a room-temperature molten salt (RTMS) with 2,4,6-trinitrophenolate anion. The RTMS is immiscible with water (W) and forms a stable RTMS/W interface. It has been shown that the RTMS/W interface can be electrochemically polarized. A well-defined voltammetric wave due to the transfer of thiocyanate ion across the RTMS/W interface was observed within the potential window. This is the first example of a polarized RTMS/W interface.

References

Nov 20, 2001·Analytical Sciences : the International Journal of the Japan Society for Analytical Chemistry·H Katano, M Senda

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Citations

Mar 4, 2006·Analytical Sciences : the International Journal of the Japan Society for Analytical Chemistry·Toshihide TsukataniNaoki Hirayama
Oct 11, 2008·Analytical Sciences : the International Journal of the Japan Society for Analytical Chemistry·Takashi Kakiuchi
Oct 11, 2008·Analytical Sciences : the International Journal of the Japan Society for Analytical Chemistry·Naoya NishiTakashi Kakiuchi
Aug 18, 2010·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Takashi KakiuchiNaoya Nishi
Jan 15, 2020·Analytical Sciences : the International Journal of the Japan Society for Analytical Chemistry·Naoya Nishi

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