Ir-catalyzed C-H activation in the synthesis of borylated ferrocenes and half sandwich compounds

Chemical Communications : Chem Comm
Anupama DattaHerbert Plenio

Abstract

The complex generated from 1/2[Ir(OMe)(cod)]2 and 4,4'-di-tert-butyl-2,2'-bipyridine catalyzes the regioselective borylation of ferrocenes, CpMn(CO)3 and CpMo(CO)3CH3 with a stoichiometric amount of B2pin2.

References

Jun 14, 2000·Chemistry : a European Journal·H PlenioA Sehring
Nov 8, 2001·Journal of the American Chemical Society·C J YuT J Meade
Mar 28, 1996·Chemical Reviews·Neil G. Connelly, William E. Geiger
Sep 17, 2003·Accounts of Chemical Research·Li-Xin DaiXue-Long Hou
Jan 8, 2004·Journal of the American Chemical Society·Jonas OxgaardRoy A Periana
Jan 23, 2004·Chemical Communications : Chem Comm·Chantal PaquetIan Manners

❮ Previous
Next ❯

Citations

Jul 2, 2009·Chemical Communications : Chem Comm·Li DangTodd B Marder
Dec 5, 2012·Beilstein Journal of Organic Chemistry·Satoshi TakebayashiTakanori Shibata
May 15, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Luis A López, Enol López
Sep 23, 2006·Chemistry : a European Journal·Yiu-Keung SauWa-Hung Leung
Apr 14, 2019·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Siyi DingPengfei Li
Apr 1, 2008·Journal of the American Chemical Society·Haitao ZhaoZhenyang Lin
Dec 24, 2009·Chemical Reviews·Ibraheem A I MkhalidJohn F Hartwig
Mar 11, 2008·Journal of the American Chemical Society·Marius V CâmpianDavid Williamson

❮ Previous
Next ❯

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.