IR spectroelectrochemical study on UVO2+ complex: first evidence for weakening of U[double bond]O bond strength in uranyl moiety with reduction from U(VI) to U(V)

Inorganic Chemistry
Koichiro Mizuoka, Yasuhisa Ikeda

Abstract

We have obtained the first evidence that the U[double bond]O bond strength in uranyl moiety is weakened with the reduction from U(VI)O(2)(2+) to U(V)O(2)(+) from the IR spectroelectrochemical study on U(VI)O(2)(saloph)DMSO and [U(V)O(2)(saloph)DMSO](-) (saloph = N,N'-disalicylidene-o-phenylenediaminate, DMSO = dimethyl sulfoxide) complexes with the thin layer electrode cell for IR measurements.

References

Jun 12, 2001·Inorganic Chemistry·L GagliardiB O Roos

❮ Previous
Next ❯

Citations

Oct 10, 2006·Chemical Communications : Chem Comm·Jean-Claude BerthetMichel Ephritikhine
Mar 26, 2009·Chemical Communications : Chem Comm·Pawel HoregladMarinella Mazzanti
Aug 8, 2009·Chemical Communications : Chem Comm·Christopher R Graves, Jaqueline L Kiplinger
Oct 20, 2010·Chemical Communications : Chem Comm·Victor MougelMarinella Mazzanti
Nov 8, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Mohammad AzamEdwin Kroke
Nov 6, 2010·Chemistry : a European Journal·Victor MougelMarinella Mazzanti
May 15, 2008·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Gary S GroenewoldNick Polfer
Apr 22, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Jean-Claude BerthetMichel Ephritikhine
Jan 27, 2019·Physical Chemistry Chemical Physics : PCCP·Krishnamoorthy Arumugam, Neil A Burton
Jul 24, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Koichiro TakaoChristoph Hennig
May 8, 2019·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Krishnamoorthy Arumugam, Neil A Burton
Jan 1, 2008·The Journal of Physical Chemistry. a·Gary S GroenewoldWibe A de Jong
Dec 2, 2009·Inorganic Chemistry·Michael F SchettiniTrevor W Hayton
Sep 17, 2009·Inorganic Chemistry·Koichiro TakaoChristoph Hennig
Oct 10, 2008·Inorganic Chemistry·Nebebech BelaiChristopher L Cahill
Jul 17, 2019·Environmental Pollution·Jie DingChuanqin Xia
Jul 6, 2018·Inorganic Chemistry·Aaron M TondreauPing Yang
May 6, 2020·Inorganic Chemistry·Sayandev ChatterjeeSamuel A Bryan

❮ Previous
Next ❯

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.